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We report in this paper on the electrochemical formation of nickel tetrasulfonated phthalocyanine (NiTSPc) based films on bulk Pt disk microelectrodes (diameter d = 50 μm) and thin-film Pt microdisk (diameter d = 10 μm) arrays for the realisation of Pt bas ...
Solutions of the strong complexing agent ethylenediaminetetraacetic acid (EDTA) and Cu, Pb, Cd, Al, and Fe(III) were examined by electrospray mass spectrometry (ES/MS). Uncomplexed EDTA and metal-EDTA complexes survive the electrospray process intact and c ...
The use of many plastic packaging materials such as PVC, PAN, etc. to protect food and beverages is restricted because of toxicity and recycling problems and there is a need for the development of new packaging materials with good gas barrier properties. P ...
The diffusion of Mn, Cr, and Ti in single crystalline copper was investigated in the temperature range between 582 and 800 K, 639 and 829 It and 621 and 747 K, respectively. Ion beam sputtering in combination with secondary ion mass spectrometry (SIMS) was ...
A review, with 9 refs., is given on trace element anal. by mass spectrometry (MS) and potentiometric stripping anal. (PSA). The key question of the problem is detn. of the structure of the samples (i.e. distribution functions and concns. of atoms, mols., c ...
"Thermal desorption experiments" were carried out during which heavy metal evaporation was studied by on-line monitoring. This could be achieved by the use of a tubular furnace connected to a heavy metal detector, i.e. an ICP-OES (inductively coupled plasm ...
The binding of metal ions to self-assembled nitrilotriacetic acid (NTA)-modified thioalkane monolayers was monitored by impedance spectroscopy via a capacitance change of the blocking gold electrode. Binding to a fluorescent NTA-derivative and the native N ...
This study explores the potential of MALDI-TOF MS for the mass measurement of large non-covalent protein complexes. The following non-covalent complexes have been investigated: aerolysin from Aeromonas hydrophila (335 kDa) and α-haemolysin from Staphylococ ...
Particle formation has been investigated experimentally from the initial molecular precursors up to the final micron-sized particles in a low pressure silane rf capacitive discharge. Neutrals and ions were studied by quadrupole mass spectrometry in power-m ...
The time-resolved fluxes of negative polysilicon hydride ions from a power-modulated rf silane plasma have been measured by quadrupole mass spectrometry and modeled using a simple polymerization scheme. Experiments were performed with plasma parameters sui ...
