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A new tool for the study of polymerization under supercritical conditions - preliminary results

Publications associées (39)

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Photocatalytic and Electrocatalytic Reduction of Carbon Dioxide in Pressurized Systems

Patrick Voyame

The depletion of carbon-based fossil fuels and the rise in atmospheric carbon dioxide concentration will force an inevitable change in the future global energy landscape. CO2 reduction presents the advantages of decreasing its atmospheric concentration and ...

EPFL2016

Impact of water activity on the stability of ettringite

Karen Scrivener, Thomas Matschei

The stability of ettringite as function of temperature and water vapour pressure was studied on synthetic samples using X-ray diffraction, thermogravimetric analysis, sorption balance measurements and different calorimetry techniques. Crystalline ettringit ...

Pergamon-Elsevier Science Ltd2016

Apparatus for salt separation under supercritical water conditions

François Maréchal, Daniel Favrat, Adriano Viana Ensinas, Alberto Mian

Apparatus for salt separation (2) under supercritical water conditions, comprising a heat exchanger (4) and a fluidized bed reactor (6). The fluidized bed reactor comprising a supercritical water pressure containing wall (8) defining therein a fluidized be ...

2016

Thermal Behavior of Methylammonium Lead-Trihalide Perovskite Photovoltaic Light Harvesters

Michael Graetzel, Mohammad Khaja Nazeeruddin, Peng Gao, Amalie Dualeh

Recently organicinorganic hybrid perovskites have attracted attention as light harvesting materials in mesoscopic cells. While a considerable number of deposition and formation methods have been reported for the perovskite crystalline material, most involv ...

Amer Chemical Soc2014

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The electrochemical oxidation and reduction of decamethylferrocene is demonstrated in supercritical carbon dioxide at a macro gold disc electrode at 100 bar and 313 K. Fast mass transport effects were exhibited and the corresponding steady-state voltammetr ...

Royal Soc Chemistry2013

Methods for determination of degree of reaction of slag in blended cement pastes

Karen Scrivener, Emmanuel Gallucci, Vanessa Kocaba

To measure the degree of reaction of slag in blended pastes, five methods were studied. Selective dissolution and differential scanning calorimetry are shown to be unreliable, SEM-BSE-IA-mapping is time consuming, but does provide good results with a reaso ...

Elsevier2012

Interfacial Photoreduction of Supercritical CO2 by an Aqueous Catalyst

Hubert Girault, Manuel Alejandro Méndez Agudelo, Patrick Voyame

Not just a solvent anymore: CO2 reduction under supercritical conditions was achieved in a biphasic water–supercritical CO2 system using an aqueous soluble catalyst (see picture). The introduction of such an interface provides a suitable reaction medium wh ...

2011

The technique of reaction calorimetry adapted for use with reactions in supercritical fluids was used to study some safety aspects of the free-radical dispersion polymerization of methyl methacrylate in scCO2. The reaction heat rate profile was found to ch ...

Wiley-Blackwell2009

A complete anal. of the heat flow equation in reaction calorimetry with supercrit. fluids is presented. An esp. developed reaction calorimeter is employed to study the challenges introduced by the supercrit. state of the reaction mixt. and the particularit ...

2008

The PhD thesis deals with the optimization of the reaction calorimetry technique to monitor chemical reactions in supercritical fluids. The aim is to develop this thermal analysis technique to monitor the heat released by a chemical reaction in a high pres ...

EPFL2008