Recent Advances in the Liquid-Phase Synthesis of Metal Nanostructures with Controlled Shape and Size for Catalysis
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Two N,N-bis(diphenylphosphino)-amine ligands [amine = 4-aminomorpholine (L-1) or 1-amino-4-methylpiperazine (L-2)] and their Pd(II) complexes were synthesised and characterised by IR and NMR spectroscopies. The structures of ligand L-1 and both complexes C ...
Reactions between gas molecules, e.g. H-2 and CO2 and solids take place at the surface. The electronic states and the local geometry of the atomic arrangement determine the energy of the adsorbate, i.e. the initial molecule and the transition state. Here w ...
The catalytic properties of Pd trigger a strong interest on the related catalysis by Au-Pd nanoparticles. However, the analysis of such phenomena was complicated so far by the presence of capping. Using x-ray irradiation, we could produce uncapped Au-Pd na ...
Ruthenium complexes, in particular cyclopentadienyl ruthenium (II) derivatives, catalyze a vast number of transformations in the field of homogenous catalysis. Herein we describe the first synthesis of efficient chiral cationic cyclopentadienyl ruthenium ( ...
Linear free energy scaling relationships and volcano plots are common tools used to identify potential heterogeneous catalysts for myriad applications. Despite the striking simplicity and predictive power of volcano plots, they remain unknown in homogeneou ...
The catalytic properties of Pd have triggered a strong interest in the related catalysis by Au–Pd nanoparticles. However, the analysis of such phenomena has been complicated so far due to the presence of capping. Using X-ray irradiation, we produced uncapp ...
