Time-resolved measurement of difluoromethylene radical formation in the infrared multiphoton dissociation of chlorodifluoromethane
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The optical properties of small noble metal clusters have been studied by absorption and fluorescence for sizes between 1 and 10 atoms. The experimental technique consists in depositing size-selected clusters in a neon matrix and analyzing with a spectrome ...
Photoacoustic spectroscopy is a widely recognised technique to measure trace gases at parts-per-million (ppm) or parts-per-billion (ppb) level using semiconductor laser in the near infrared range. This technique is based on the generation of an acoustic wa ...
Multi-hydrogenated compounds detection based on photoacoustic (PA) spectroscopy is reported. Three near-infrared semiconductor lasers are used with a resonant PA cell operated in its first longitudinal mode to monitor methane, water vapour and hydrogen chl ...
Infrared spectroscopy using semiconductor lasers is a promising technique for trace gas detection. It allows a continuous and real time monitoring of several species, with a high sensitivity and a good selectivity. Among all the possible methods two are pa ...
Industrial laser precision machining is predominately based on pulsed Nd:YAG lasers operated at a wavelength of 1.06 µm in a free running pulse regime. The objective of this thesis work has been to investigate second and third harmonic generation for such ...
High-resolution absorption spectra of adenine, 9-methyladenine and 2-aminopurine in helium nanodroplets have been recorded. In contrast to molecular beam experiments, large variations in linewidths are observed for adenine and 9-methyladenine. At the same ...
We report direct absorption spectroscopic detection of ozone at ambient pressure with a pulsed, DFB quantum-cascade laser (QCL) tuned within 1044-1050 cm(-1) by temperature scanning. Wavelength calibration curves were derived from FTIR and CO2 spectra and ...
We describe a new apparatus that combines pulsed laser excitation in a molecular beam with surface-science methods for preparation of clean single-crystal surfaces and detection of adsorbates to enable state-selected studies of gas-surface reaction dynamic ...
We present a novel high power femtosecond infrared laser source, based on a three-stage chirped-pulse amplification scheme. Owing to the high power output of the Ti:sapphire amplifiers, it becomes routinely possible to produce femtosecond infrared laser pu ...
Spectroscopic measurements on ethylene were performed using a quasi-room-temperature quantum cascade (QC) laser operated in pulsed mode in the 10.3 μm range. Using transmission spectroscopy, a broadening of the ethylene absorption spectrum was observed wit ...