New types of triple-layer membranes were fabricated using multi-step impregnation of Nation in electrospun webs based on bead-free nanofibers of sulfonated poly(ether sulfone) (SPES). The results showed that the fabricated nanofiber-filled membrane owing to its reduced methanol permeability as well as sufficient proton conductivity and membrane selectivity can be used as a promising proton exchange membrane for direct methanol fuel cell (DMFC) applications. The single cell DMFC performance results revealed that the SPES nanofiber-based triple-layer membranes have higher electrochemical performance than commercial Nation membranes. (C) 2011 Elsevier B.V. All rights reserved.
Jan Van Herle, Suhas Nuggehalli Sampathkumar, Khaled Lawand, Zoé Mury
Sophia Haussener, Saurabh Yuvraj Tembhurne, Alexandre Dominique M. Cattry, Matthieu Jonin, Mahendra Patel