Thiol-Ene Click Chemistry as a Tool for a Novel Family of Polymeric Ionic Liquids
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Replacing the liq. electrolyte in lithium batteries by a solid has been a long-standing goal of the battery industry due to the promise of better safety and the potential to produce batteries with higher energy densities. Recently, sym. polystyrene-block-p ...
This paper focuses on the prediction of temperature profiles on the surface of Lithium-ion cells. In particular, the paper proposes the adoption of the impulse response technique to predict cell surface temperatures consequent to generic discharge conditio ...
Within the context of the electrical circuit modeling of batteries, this paper proposes an improvement of the most common electric equivalent circuit used for Lithium cells. The main improvement is based on the modeling of the so-called charge redistributi ...
Chem. degrdn. at electrode/electrolyte interfaces in high-energy storage devices, such as Li-ion batteries, imposes durability challenges that affect their life and cost. In oxide electrodes, degrdn. is linked to the presence of redox active transition met ...
A method for the Friedel-Crafts-type insertion reaction of acetylene with acid chlorides in chloroaluminate ionic liquids is presented. The use of Ionic liquids not only serves to avoid the use of carbon tetrachloride or 1,2-dichloroethane but also suppres ...
There is considerable interest in developing solid electrolytes for rechargeable lithium batteries as they have the potential to increase both energy d. due to incorporation of a lithium metal anode and safety of batteries due to the fact that they are non ...
We review herein several important aspects of surface chemistry in Li-ion batteries, and discuss the use of ionic liquids (ILs) for rechargeable Li batteries. We explored the suitability of ILs for 5 V cathodes and Li-graphite anodes. Some advantages of th ...
Some fundamental challenges are shaping the world we live in, and the need for alternative materials and energies is one of the most prominent issues of this century, especially in the light of global warming and energy need. Another crucial point concerns ...
This work describes different strategies for the detection of biologically relevant analytes. The main goal was to achieve sensing in water, which is a prerequisite for application to real biological samples. In several cases, we could demonstrate that our ...
The feasibility of spatially resolved Raman spectroscopy probing diffusion multiples as a high-throughput method to study phase transformations in Li-ion conductors is demonstrated. The method is applied to the pseudobinary LiBH 4-LiI system, which shows h ...