Synthesis of borasiloxane-based macrocycles by multicomponent condensation reactions in solution or in a ball mill

Rosario Scopelliti, Kay Severin, Albert Ruggi, Mirela Pascu
2013
Article

Résumé

Large macrocycles containing imine and borasiloxane links are obtained in polycondensation reactions of 4-formylbenzeneboronic acid, t-Bu2Si(OH)2, and diamines. The multicomponent reactions can be performed in solution or – advantageously – by mechanochemical syntheses in a ball mill.

Source officielle

https://infoscience.epfl.ch/record/183649?ln=fr

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Synthesis of borasiloxane-based macrocycles by multicomponent condensation reactions in solution or in a ball mill

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