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Inertisation of heavy metals in municipal solid waste incineration fly ash by means of colloidal silica – a synchrotron X-ray diffraction and absorption study

Publications associées (43)

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The impact of synthetic amorphous silica (E 551) on differentiated Caco-2 cells, a model for the human intestinal epithelium

Heinrich Hofmann

For several decades, food-grade synthetic amorphous silica (SAS) have been used as a technological additive to reduce caking of food powders. Human exposure is thus inevitable and safety concerns are taken seriously. The toxicity of silica in general and S ...

PERGAMON-ELSEVIER SCIENCE LTD2020

Mining of rare earth metals from hydro mineral resources in Siberia: trends and prospects

Siberian scientists showed by their scientific investigations that brines of Siberian Platform are a very important hydro mineral resource for economical development of the East Russia. Prospects for the integrated mining of the hydromineral resources in R ...

A World Resources Forum Production, PSI2017

Alkali uptake in calcium alumina silicate hydrate (C-A-S-H)

Karen Scrivener, Barbara Lothenbach, Émilie Michèle L'Hôpital

Uptake of the alkalis K and Na by calcium silicate hydrate (C-S-H) and calcium alumina silicate hydrate (C-A-S-H) of molar Ca/Si ratios = 0.6 to 1.6 and molar Al/Si ratio = 0 or 0.05 has been studied at 20 degrees C. Alkalis are thought to be bound in the ...

Pergamon-Elsevier Science Ltd2016

Identifying the intermediate species along a reaction pathway is a first step towards a complete understanding of the reaction mechanism, but often this task is not trivial. There has been a strong on-going debate: which of the three intermediates, the CHI ...

Royal Soc Chemistry2015

Biomineralization processes leading to complex solid structures of inorganic material in biological systems are constantly gaining attention in biotechnology and biomedical research. An outstanding example for biomineral morphogenesis is the formation of h ...

Mdpi Ag2015

Characterizing the Structure and Defect Concentration of ZnO Nanoparticles in a Colloidal Solution

Majed Chergui, Thomas James Penfold, Camelia Borca, Marco Eli Reinhard, Thomas Charles Henry Rossi, Mercedes Hannelore Rittmann-Frank, Jochen Rittmann

The structure and defect concentration of colloidal solutions of ZnO nanoparticles, synthesized by a sol gel procedure (SG-NP), as well as commercially available ZnO nanoparticles (SA-NP) are investigated by UV-vis absorption spectroscopy, transmission ele ...

Amer Chemical Soc2014

Calcium silicate hydrate (C-S-H) is the main hydrate phase in Portland cements. Its composition varies depending on the Ca/Si ratio and on the presence of other ions such as aluminium (called CA- S-H) or alkalis. This thesis aimed to study the compositi ...

EPFL2014

A particularly difficult challenge in the chemistry of nanomaterials is the detailed structural and chemical analysis of multicomponent nano-objects. This is especially true for the determination of spatially resolved information. In this study, we demonst ...

AMER CHEMICAL SOC2014

Silica-surface reorganization during organotin grafting evidenced by Sn-119 DNP SENS: a tandem reaction of gem-silanols and strained siloxane bridges

David Lyndon Emsley, Aaron James Rossini

Grafting reactive molecular complexes on dehydroxylated amorphous silica is a strategy to develop ``single-site'' heterogeneous catalysts. In general, only the reactivity of isolated silanols is invoked for silica dehydroxylated at 700 degrees C ([SiO2-700 ...

2014

Core/shell nanoparticles having metallic silver nanoparticle cores of similar to 38 nm in diameter and silica shells of different thicknesses ranging from similar to 3.6-20 nm were prepared. For the silica coating, a slightly modified Stober method was use ...

RSC Publishing2013