Huge critical current density and tailored superconducting anisotropy in SmFeAsO0.8F0.15 by low-density columnar-defect incorporation

Iron-based superconductors could be useful for electricity distribution and superconducting magnet applications because of their relatively high critical current densities and upper critical fields. SmFeAsO0.8F0.15 is of particular interest as it has the highest transition temperature among these materials. Here we show that by introducing a low density of correlated nano-scale defects into this material by heavy-ion irradiation, we can increase its critical current density to up to 2 x 10(7) A cm(-2) at 5 K-the highest ever reported for an iron-based superconductor-without reducing its critical temperature of 50 K. We also observe a notable reduction in the thermodynamic superconducting anisotropy, from 8 to 4 upon irradiation. We develop a model based on anisotropic electron scattering that predicts that the superconducting anisotropy can be tailored via correlated defects in semimetallic, fully gapped type II superconductors.

Normal state transport properties of novel superconductors

Balazs Sipos

The discovery of high temperature superconductivity in the cuprates in 1986 has boosted the research in strongly correlated materials. One strong motivation was and stays the understanding the high-Tc phenomenon with the hope that one can ultimately engineer new materials with even higher Tc. Besides the in-depth investigation of cuprates, there is a strong tendency in the solid state community to find new superconductors, which by themselves are interesting for applications, or by their properties they can contribute to the understanding of the high-Tc phenomenon. The program of my doctoral thesis was three-fold: i) to address one important issue in the cuprate superconductors, that of the role of homogeneity in the underdoped part of the phase diagram; ii) what is the effect of disorder in MgB2 superconductor, which has high potentials for applications; iii) to discover new superconductors in the family of transition metal dichalcogenides. All these materials are in some sense unconventional superconductors. The cuprates by their high Tc and the symmetry of the order parameter, MgB2 by its two-band superconductivity and Tc of 39 K, and the dichalcogenides by the appearance of superconductivity on the background of competing interactions. Measurements of transport properties, such as resistivity and thermoelectric power, were used to get insight in the behavior of these materials. Besides temperature as variable, I applied high pressure, extreme magnetic fields and controlled disorder introduced by fast electron irradiation. In the first part I present the pressure dependent study of two members of the transition metal dichalcogenides having 1T structure, 1T-TiSe2 and 1T-TaS2, where superconductivity was never observed in a pristine sample. 1T-TiSe2 has a CDW phase below 220 K which origin, weather it is driven by an excitonic mechanism or by a Jahn-Teller distortion, is an ongoing question. By applying pressure I showed that the pristine sample is superconducting in the pressure range of 2.0–4.0 GPa. This range remarkably coincides with the short range fluctuating CDW before its disappearance at the upper pressure value. If CDW is due to excitonic interactions than our observations suggest that it can be at the origin of superconductivity, as well. The second dichalcogenide is the 1T-TaS2, where a Mott-insulator phase appears on the top of a commensurate CDW. By applying pressure I was able to melt that Mott-phase, and reveal that the material is superconducting above 2.5 GPa with Tc of 5.9 K. Unexpectedly, superconductivity is born from a nonmetallic phase, and stays remarkably stable up to the highest applied pressure of 24 GPa. In the second part I tried to give my contribution to the field of high-Tc superconductors. I carefully selected few high quality underdoped Bi2Sr2PrxCa1-xCu2O8-δ sample, to address the nature of the low temperature ground state by applying high magnetic field. Although former measurements by other groups showed that at high underdoping, the ground state is an insulator, I found that a sample with as low Tc as 15 K exhibits metallic behavior up to 60 T. Furthermore, I showed that a inhomogeneous distribution of the doping atoms can completely mask the intrinsic normal state of a high-Tc superconductor. In the last part of my thesis I focused on the two-band superconductor MgB2 by studying the scattering between the bands by the means of the Matthiessen's rule. I made a systematic study of the influence of defects created by fast electron irradiation, and found that the the Matthiessen's rule is satisfied for the defect concentration range I induced. I further compare the influence of defects on the critical temperature and the residual resistivity in MgB2 with superconductors with various order parameters, and found that the decrease-rate of Tc in our system is within the range of a response of a superconductor with an s-wave order parameter.

EPFL2008

Numerical modelling of high temperature superconducting tapes and cables

Francesco Grilli

This Ph.D. thesis is focused on the numerical modelling of high-Tc superconductors (HTS) at the operating temperature of 77 K (liquid nitrogen). The purpose of numerical modelling is to precisely calculate the current and field distributions inside HTS devices (tapes, cables) and the corresponding AC losses, which are one of the most important limiting factors for a large-scale application of such materials. From the electrical point of view, superconductors are characterized by a strongly non-linear voltage-current relation, which defines the transition from superconducting to normal state. In the case of HTS, the steepness of this transition is smoother than for low-Tc superconductors (LTS), so that the commonly used critical state model (CSM) gives a too simplified representation of their electromagnetic behaviour and can be used for a qualitative description only. In this thesis the finite element method (FEM) has been used for precisely computing the current and field distributions as well as for evaluating the AC losses in HTS devices. The superconducting transition is modelled with a power-law relation, E(J) = Ec(J/Jc)n, which is derived from the fit of transport measurements. Firstly, the results obtained with the software package FLUX3D on multi-filamentary tapes have been validated by means of a comparison with the ones obtained by another software package (FLUX2D). The results from FLUX2D, having already been successfully compared with experimental measurements within the framework of two previous Ph.D. theses at LANOS, have been used as reference. Secondly, two power-law models, which take into account the spatial variation of the critical current density inside HTS tapes and its strongly anisotropic dependence on the magnetic field, have been implemented in FLUX3D. In most cases, this latter dependence is extremely important, since the transport capacity of the superconductor is considerably reduced (and its power loss sensibly increased) by the presence of a magnetic field. Afterwards, FEM modelling of HTS tapes has been extended to cables. HTS cables are in general composed by different layers of several tapes and have a quite complex three-dimensional structure: in fact, the layers are wound around a central cylindrical support with different pitch lengths and relative winding orientations, in order to obtain a uniform repartition of the transport current among the layers, which minimizes the total AC losses. For overcoming the difficulties of a direct 3D FEM simulation, a simple electrical model, which allows to find the optimal pitch lengths and whose results are the input data for a 2D FEM evaluation of the AC losses, has been developed. FEM computations have also been used to investigate the influence of the non-uniformity of the tape properties (contact resistance, critical current, power index) on the global loss performance of a single-layer HTS cable. As an alternative to FEM computations, an equivalent circuit model of HTS cables has been utilized. It describes the cable from the macroscopic point of view and allows to compute the current repartition among the layers and the corresponding AC losses, without the necessity of having detailed information about individual tapes. In the framework of the European project BIG-POWA, I have collaborated to the assembling process of a HTS power-link at the Pirelli Labs, in the Milan region, Italy. Finally, 3D simulations have been performed to extensively study the coupling effect between two superconducting filaments via the resistive matrix, which is a typical case where analytical solutions exist for very peculiar geometries and physical conditions only. FEM simulations have been utilized to study the dependence of the filament coupling on the physical and geometrical parameters of the conductors.

EPFL2004

Signatures of quantum criticality in the thermopower of Ba(Fe1-xCox)(2)As-2

Stevan Arsenijevic, László Forró, Richard Gaal

We demonstrate that the thermopower (S) can be used to probe the spin fluctuations (SFs) in proximity to the quantum critical point (QCP) in Fe-based superconductors. The sensitivity of S to the entropy of charge carriers allows us to observe an increase of S/T in Ba(Fe1-x Co-x)(2)As-2 close to the spin-density-wave (SDW) QCP. This behavior is due to the coupling of low-energy conduction electrons to two-dimensional SFs, similar to heavy-fermion systems. The low-temperature enhancement of S/T in the Co substitution range 0.02 < x < 0.1 is bordered by two Lifshitz transitions, and it corresponds to the superconducting region, where a similarity between the electron and nonreconstructed hole pockets exists. The maximal S/T is observed in proximity to the commensurate-to-incommensurate SDW transition, for critical x(c) approximate to 0.05, close to the highest superconducting T-c. This analysis indicates that low-T thermopower is influenced by critical spin fluctuations which are important for the superconducting mechanism.