Hyperpolarization of Deuterated Metabolites via Remote Cross-Polarization and Dissolution Dynamic Nuclear Polarization
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New NMR techniques are described for transferring transverse magnetization between scalar-coupled nuclei in the rotating frame. The methods involve simultaneous spin-locking of two selected spins A and X, using cosinusoidal modulation of the radio frequenc ...
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A technique is proposed which simplifies the study of spin-lattice relaxation in multilevel nuclear spin systems. The introduction of non-participating "spy" nuclei, which interact with the nuclei under investigation through scalar or dipolar coupling, m ...
For most of the last forty years, the techniques of Dynamic Nuclear Polarization (DNP) have been confined to particle-physics laboratories building polarized targets, but recently it has been shown that samples similar to a solid target can be transformed ...
In two influential paper, Ernst and coworkers argued that cross-polarization, originally proposed by Hartmann and Hahn, can be very useful in isotropic liqs. to transfer coherence between scalar-coupled nuclei such as protons and carbon-13 (Maudsley, A. A. ...
By analogy to heteronuclear systems, coherence can be transferred adiabatically in the rotating frame between two selected spins I and S belonging to a homonuclear network of scalar-coupled spins. In contrast to cross polarization with const. radiofrequenc ...
