Electrochemical reduction of CO2 in organic solvents catalyzed by MoO2
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NOVELTY - A 2-butene-1,4-diol is prepared by hydrogenating 2-butyne-1,4-diol in the presence of a structured catalyst and in the absence of a solvent. USE - For preparing 2-butene-2,4-diol that is an important industrial intermediate in the preparation of ...
The chemical and electrochemical promotion of highly dispersed nanofilm Rh catalysts (dispersion: about 10 %, film thickness: 40 nm) has been investigated for the first time. To this end Rh metal was sputter-deposited, either on a purely ionic conductor (8 ...
The synthesis and characterization of a series of cobalt(III) complexes of the general type Co(N2O2)(L-2) are described. The N2O2 Schiff base ligands used are Me-salpn (H2Me-salpn = N,N'-bis(methylsalicylidene)-1,3-propylenediamine) (1-3) and Me-salbn ...
Linear amides, prepd. in one step by the Ugi four-component reaction, were converted to 3,4-dihydroquinoxalin-3-ones or to 2-(2-oxoindolin-1-yl)acetamides dependent on the catalytic conditions. While microwave irradn. was found to be determinant on the rea ...
We have studied the retention indices of 127 volatile substances on a C-78-paraffin and on its seven nearly isochor and isomorphous polar derivatives over a temperature range of 90-210 A degrees C. The retention index of a substance on the C-78 paraffin ha ...
Control of the N-glycosylase reaction by the DNA repair enzyme, MutY, entails the organization of solvent molecules. Classical molecular dynamics and QM/MM simulations were used to investigate the solvent and environment effects contributing to catalysis. ...
Bio synthetic natural gas (Bio-SNG) is being proposed as an alternative to the natural gas of fossil origin (NG) [1]. Bio-SNG consists mainly of CH4 (at least 95%mol), has a high heating value (e.g. 10 kWh/m3N), and respects the quality standards of the NG ...
A heterobimetallic Ru(II)-Rh(I) complex has been identified as a potent catalyst precursor for the Oppenauer-type oxidation of alcohols. With 0.1-0.5 mol% of this complex and K2CO3 as the co-catalyst, it is possible to oxidize secondary and primary alcohol ...
A new experimental set-up, coupling electrochemistry and mass spectroscopic techniques, for the investigation of a solid electrochemical cell under high vacuum conditions (HV) is presented. Two configurations are realized allowing the investigation of both ...
The diphosphane-substituted clusters [Ru-3(CO)(10)(dppe)] and [Ru-3(CO)(8)(dppe)(2)] [dppe = 1,2-bis(diphenylphosphanyl)ethane] are shown to catalytically hydrogenate diphenylacetylene. This process is highly solvent-dependent with fragmentation dominating ...