Synthesis of Electron-Rich Uranium(IV) Complexes Supported by Tridentate Schiff Base Ligands and Their Multi-Electron Redox Chemistry
Publications associées (48)
Graph Chatbot
Chattez avec Graph Search
Posez n’importe quelle question sur les cours, conférences, exercices, recherches, actualités, etc. de l’EPFL ou essayez les exemples de questions ci-dessous.
AVERTISSEMENT : Le chatbot Graph n'est pas programmé pour fournir des réponses explicites ou catégoriques à vos questions. Il transforme plutôt vos questions en demandes API qui sont distribuées aux différents services informatiques officiellement administrés par l'EPFL. Son but est uniquement de collecter et de recommander des références pertinentes à des contenus que vous pouvez explorer pour vous aider à répondre à vos questions.
Ru(II) and Os(II) p-cymene dichloride complexes with either a pta (1,3,5-triaza-7-phosphatricyclo[3.3.1.1]decane) or [pta-Me]Cl ligand which exhibit anticancer activity were prepd. and characterized by 1H and 31P NMR spectroscopy and mass spectrometry. Thr ...
The nature of the bonding in ethylene and h2-P4 complexes, M(C2H4)2+ and M(h2-P4)2+, of group 11 metal cations (M = Cu, Ag, Au) has been explored by d. functional calcns. On the basis of the evaluation of symmetry orbitals, the contributions from the inter ...
The invention provides a novel podate ligand H4L[1,2,4,5-tetrakis(pyrazol-1-ylmethyl-3-carboxylic acid)benzene] and to complexes comprising the ligand and a metal ion. Pharmaceutical compositions and methods of making and using the metal-podate complex ...
Heterobimetallic complexes where half-sandwich complexes of ruthenium(II), rhodium(III) and iridium(III) are connected by three bromo-bridges to Re(CO)3 have been prepd. from metathesis reactions of [RuBr(m-Br)(h6-arene)]2 (arene = C6H6, C6H3Et3-1,3,5 or p ...
The C2-sym. electron-poor ligand (R)-BINOP-F (4; (R)-2,2'-[bis(pentafluorophenyl)phosphinoxy]-1,1'-binaphthalene) was prepd. by reaction of (R)-BINOL ((R)-1,1'-binaphthalene-2,2'-diol) with bromobis(pentafluorophenyl)phosphine in the presence of NEt3. The ...
The hydrogenation of benzene and other arenes under aqueous-organic biphasic conditions is evaluated using the ruthenium complexes Ru(eta(6)-C10H14)(pta)Cl-2 (pta=1,3,5-triaza-7-phosphaadamantane), Ru(eta(6)-C10H14)(tppts)Cl-2 (tppts=tris-3-sulfonatophenyl ...
The cyanobacterial metabolite anachelin, postulated to serve as a biological ligand to Fe (siderophore), is composed of a fascinating blend of polyketide, peptide, and alkaloid building blocks. In particular, the latter consists of a N,N-dimethyltetrahydro ...
Conversion of unactivated olefins to azides was achieved with high Markovnikov selectivity for a broad range of alkenes by using 6 mol % Co(BF4).6H2O and ligand I, with 3 equiv of tosyl azide as the nitrogen source and simple silanes (e.g., PhSiH3, tetrame ...