Controlled Thermolysis of Uranium (Alkoxy) siloxy Complexes: A Route to Polymetallic Complexes of Low-Valent Uranium
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Characteristics of the spent nuclear fuel (SNF) are typically calculated, requiring validation a priori. The validation process relies on the difference between calculations and measurements, namely the bias. Usually, predicting the bias based on benchmark ...
Wyoming-type bentonite is one of the materials to be used as part of the Engineered Barrier System (EBS) in deep geological disposal facilities for the safe disposal of spent nuclear fuel.In the KBS-3 type repository, the canisters containing the spent fue ...
Herein, we report the redox reactivity of a multimetallic uranium complex supported by triphenylsiloxide (−OSiPh3) ligands, where we show that low valent synthons can be stabilized via an unprecedented mechanism involving intramolecular ligand migration. T ...
Decay heat calculations of spent nuclear fuel (SNF) using Polaris and ORIGEN codes in the SCALE code sys-tem, and CASMO5 code, are validated using measurements from the Clab and GE-Morris facilities. Multiple hypothesis testing, relying on permutations and ...
PERGAMON-ELSEVIER SCIENCE LTD2022
Microstructural evolution during in-pile irradiation, radiation damage effects and fission products behavior in UO2 nuclear fuel are key issues in understanding and for the modeling of the performance as well as safety characteristics of nuclear fuels in t ...
Currently, most Spent Nuclear Fuel (SNF) is kept safely in storage either at on-site facilities or at centralized interim storage sites. Moreover, many countries face delays in implementing their waste management programmes for SNF and high-level waste dis ...
Complexes of uranium in low oxidation state have shown the ability to activate non-reactive small molecules such as N-2. However, the multi-electron transfer required for such activation remains limited in uranium chemistry. Here, we review our recent rese ...
Major uranium (U) deposits worldwide are exploited by acid leaching, known as 'in-situ recovery' (ISR). ISR involves the injection of an acid fluid into ore-bearing aquifers and the pumping of the resulting metal-containing solution through cation exchange ...
Decay heat residuals of spent nuclear fuel (SNF), i.e., the differences between calculations and measurements, were obtained previously for various spent fuel assemblies (SFA) using the Polaris module of the SCALE code system. In this paper, we compare dec ...
In the last decades, the activation of small molecules has attracted increasing attention for their use as cheap and abundant feedstock. Low-oxidation state uranium complexes have displayed high reactivity towards small molecules thanks to their unique pro ...