Dynamics and disorder in surfactant-templated silicate layers studied by solid-state NMR dephasing times and correlated line shapes
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Magnetism is largely responsible for the body centered cubic to face centered cubic structural phase transition occurring in iron at 1185 K and to many anomalies in the vicinity of the ferromagnetic to paramagnetic phase transition at 1043 K, as for instan ...
Nuclear Magnetic Resonance (NMR) spectroscopy offers many ways to investigate dynamic properties of molecules. A wide variety of experimental techniques can probe molecular dynamics on time scales that range from 10-12 to 103 seconds. Many lines of evidenc ...
We report on the magnetic excitation spectrum of the coupled-spin tetrahedral system Cu2Te2O5Cl2 using Raman scattering on single crystals. The transition to an ordered state at T-N(Cl)=18.2 K evidenced from thermodynamic data leads to the evolution of dis ...
Nuclear magnetic relaxation in the presence of paramagnetic centres has gained increasing interest in recent years partly due to its importance for contrast agents in magnetic resonance imaging. Rational design of new more efficient agents is possible as a ...
Electronic and magnetic properties of quasi-one dimensional ormore widely low-dimensional systems aswell as their related correlated electron phenomena have been at the very frontier of condensed matter physics for quite some time. The reduced dimensionali ...
C59N magnetic fullerenes were formed inside single-wall carbon nanotubes by vacuum annealing functionalized C59N molecules encapsulated inside the tubes. A hindered, anisotropic rotation of C59N was deduced from the temperature dependence of the electron s ...
The Bases of Chemical Thermodynamics: Volume 2 In this volume (volume 2), the tools necessary to study and understand systems in which chemical reactions can take place are developed. The variables of reaction are the keys to this understanding. Criteria f ...
The syntheses and single crystal X-ray structural analysis of five novel hetero- and homometallic μ3-oxo trinuclear cluster with the formula [FeIII2MII(μ3-O)(μ-O2CCH3)6(4-Rpy)3] · x(4-Rpy) · y(CH3CN) where R ) Ph for 1(Fe2Mn),2(Fe2Fe), 3(Fe2Co), 4(Fe2Ni) a ...
The Bases of Chemical Thermodynamics: Volume 1 In this volume (volume 1), the fundamental aspects of thermodynamics are presented. The first and second laws of thermodynamics are illustrated. The need to define thermodynamic temperature and the nature of e ...
We performed a photoemission investigation of the electronic structure of PrNiO3 and NdNiO3 through the first order (paramagnetic) metal to (antiferromagnetic) insulator transition. Surprisingly, the data reveal a temperature-dependent loss of spectral wei ...