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Quantum description of a rotating and vibrating molecule

Publications associées (35)

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In quantum mechanics, the Heisenberg uncertainty principle places a fundamental limit in the measurement precision for certain pairs of physical quantities, such as position and momentum, time and energy or amplitude and phase. Due to the Heisenberg uncert ...

EPFL2020

Preparation and Decay of a Single Quantum of Vibration at Ambient Conditions

Christophe Marcel Georges Galland, Vivishek Sudhir, Mitchell David Anderson, Kilian Robert Seibold, Nils Kipfer

A single quantum of excitation of a mechanical oscillator is a textbook example of the principles of quantum physics. But mechanical oscillators, despite their pervasive presence in nature and modem technology, do not genetically exist in an excited Fock s ...

2019

Methane dissociation on the steps and terraces of Pt(211) resolved by quantum state and impact site

Rainer Beck, Ana Gutiérrez González, Helen Jane Chadwick

Methane dissociation on the step and terrace sites of a Pt(211) single crystal was studied by reflection absorption infrared spectroscopy (RAIRS) at a surface temperature of 120 K. The C−H stretch RAIRS signal of the chemisorbed methyl product species was ...

American Institute of Physics2018

Combinatorics of Loop Equations for Branched Covers of Sphere

Nicolas Gerson Orantin

We prove, in a purely combinatorial way, the spectral curve topological recursion for the problem of enumeration of bi-colored maps, which are dual objects to dessins d'enfant. Furthermore, we give a proof of the quantum spectral curve equation for this pr ...

OXFORD UNIV PRESS2018

Geometric Integrators for Nonadiabatic Molecular Quantum Dynamics Induced by the Interaction with the Electromagnetic Field

Aurélien Kevin Fabrice Patoz

Understanding the elementary steps involved in a chemical reaction forms the cornerstone of physical chemistry research. One way to deepen this understanding is by studying chemical and physical processes using linear and nonlinear spectroscopic techniques ...

EPFL2017

Why are classical theories often sufficient to describe the physics of our world even though everything around us is entirely composed of microscopic quantum systems? The boundary between these two fundamentally dissimilar theories remains an unsolved prob ...

EPFL2017

Optical second harmonic generation from nanostructured graphene: a full wave approach

Olivier Martin, Jérémy Butet, Gabriel David Bernasconi, Raziman Thottungal Valapu, Bruno Majérus

Optical second harmonic generation (SHG) from nanostructured graphene has been studied in the framework of classical electromagnetism using a surface integral equation method. Single disks and dimers are considered, demonstrating that the nonlinear convers ...

2017

The Loschmidt echo is a measure of quantum irreversibility and is determined by the fidelity amplitude of an imperfect time-reversal protocol. Fidelity amplitude plays an important role both in the foundations of quantum mechanics and its applications, suc ...

Royal Soc2016

An introduction to the problem of bridging quantum and classical dynamics

Sara Bonella

Simulating the exact quantum dynamics of realistic interacting systems is presently a task beyond reach but for the smallest of them, as the numerical cost for solving the time-dependent Schrodinger equation scales exponentially with the number of degrees ...

Springer Heidelberg2015

Rotational Heisenberg Inequalities

Jean-Philippe Ansermet, Sylvain Bréchet, François Reuse, Klaus Maschke

Since their discovery in 1927, the Heisenberg Inequalities have become an icon of quantum mechanics. Often inappropriately referred to as the Uncertainty Principle, these inequalities relating the standard deviations of the position and momentum observable ...

EDP Sciences2015