A generalized Poisson and Poisson-Boltzmann solver for electrostatic environments
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The purpose of this thesis is to investigate methods for the solution of multiscale problems both from the mathematical and numerical point of view, with a particular concern on applications to flows through heterogeneous porous media. After an overview of ...
This work presents an investigation of the tribocorrosion of ruthenium in sulphuric acid solutions. The study was focused on the effect of the electrode potential on wear of ruthenium during sliding against an inert alumina ball in a reciprocating sliding ...
The electrochemical oxidation of 3,4-(methylenedioxy)phenylmethanol (piperonyl alcohol) was characterized by cyclic voltammetry (CV) and electrochemical impedance spectroscopy (EIS). Two electrochemical oxidation signals were found for piperonyl alcohol. T ...
The interface between two immiscible electrolyte solutions (ITIES), or liquid|liquid interface, provides a defect-free junction for fundamental studies of adsorption phenomena, heterogeneous charge transfer reactions, and phase-formation processes. Recent ...
Synthetic boron-doped diamond thin film is a new promising anode material. Because of its properties (high anodic stability under drastic conditions and wide potential window), it is widely investigated for numerous possible electrochemical applications su ...
Excitons and trions in a CdTe modulation-doped quantum well are investigated by picosecond three-pulse four-wave mixing experiments as a function of temperature in the low-density regime. We show that trions are mobile for high enough temperatures. The dif ...
This work deals with the modelling of electrochemical reactors with bipolar electrodes. We give a numerical model which enables us to compute electrical current and potential distributions in an electrochemical cell of any type of geometry in two and three ...
Abstract The objective of this work is the numerical simulation of the reactive laminar boundary layer which occurs in a neighbourhood of a body moving in the air. We have investigated the modelling of the reactive boundary layer when, the "chemical equili ...
The onset voltage of a colloid thruster is an important parameter in the design of micromachined thrusters. Because dimensions in MEMS thrusters are in the range of several tens of micrometers and because extractor electrodes can be only 5 μm from the capi ...
The chemical and electrochemical promotion of highly dispersed nanofilm Rh catalysts (dispersion: about 10 %, film thickness: 40 nm) has been investigated for the first time. To this end Rh metal was sputter-deposited, either on a purely ionic conductor (8 ...