Symmetry breaking in hexagonal and cubic polymorphs of BaTiO3
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We report an intrinsic strain engineering, akin to thin filmlike approaches, via irreversible hightemperature plastic deformation of a tetragonal ferroelectric single-crystal BaTiO3. Dislocations wellaligned along the [001] axis and associated strain field ...
The growth speed of (hkl) faces in the vapour phase, the absolute structure obtained by X-ray crystallography, and the value and the sign of the pyroelectric coefficient of meta-nitroaniline (mNA) were analysed in detail. The in situ observation of morpho ...
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Many perovskite materials experience a temperature-driven phase transition at the Curie temperature from a non-centrosymmetric polar ferroelectric phase to a paraelectric phase, where polarization is lost. The paraelectric phase is usually centrosymmetric ...
Ferroelectrics are usually defined as polar materials that display polarisation hysteresis. This is a functional definition. A structural definition exists too, based solely on symmetry arguments. The structural definition, useful e.g. for design of new ma ...
The influence of annealing between the Curie transition and the melting point of solvent cast polyvinylidene fluoride trifluoroethylene copolymer films on the crystalline structure, mechanical and electrical properties, and oxygen permeability is investiga ...
Flexoelectricity-the coupling between polarization and strain gradients-is a universal effect allowed by symmetry in all materials. Following its discovery several decades ago, studies of flexoelectricity in solids have been scarce due to the seemingly sma ...
Strain response of polycrystalline barium titanate (BaTiO3) was investigated under high unipolar electric field (0 to 4 kV/mm) and compressive stress (0 to 400 MPa) in the temperature range from 25 to 160 degrees C. In the vicinity of the Curie point (T-C) ...
The flexoelectric effect is the response of electric polarization to a mechanical strain gradient. It can be viewed as a higher-order effect with respect to piezoelectricity, which is the response of polarization to strain itself. However, at the nanoscale ...
A centrosymmetric stress cannot induce a polar response in centric materials; piezoelectricity is, for example, possible only in non-centrosymmetric structures. An exception is meta-materials with shape asymmetry, which may be polarized by stress even when ...