Block copolymer-directed assembly of bare metal oxide nanocrystals for energy-related devices
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Quantum dots embedded within nanowires represent one of the most promising technologies for applications in quantum photonics. Whereas the top-down fabrication of such structures remains a technological challenge, their bottom-up fabrication through self-a ...
Native coordinating ligands acquired during the chem. synthesis of colloidal nanocrystals are optimized primarily for their ability to exert control over nanocrystal size, compn., morphol., and dispersibility, and not necessarily for their final applicatio ...
The properties of metal oxide nanocrystals in energy-related devices are strongly dependent on the presence and chem. nature of ligands at their surface, and the architectures they assume in electroactive layers. A comprehensive strategy to control these a ...
In recent years, the fabrication of novel ultrathin film systems featuring multi-functionalities has been extensively studied due to their potential applications in photonics, sensors and solar cells. In a general sense, the primary goal of the present the ...
Self-assembly is the autonomous organization of components into patterns or structures without human intervention. At the molecular level, self-assembly usually involves non-covalent interactions of various natures, such as van der Waals, electrostatic and ...
Ole-ain't: Trialkyl oxonium salts are universal reagents for native-ligand stripping of carboxylate- (e.g., oleate-), phosphonate-, and amine-passivated nanocrystal thin films and dispersions to give bare or BF 4 -/DMF-passivated surfaces. Meerwein-activat ...
A review. Colloidal nanocrystal frameworks (CNFs) are a modular class of mesostructured porous materials, which are assembled from pre-formed nanocrystal building units using suitably designed block copolymer architecture-directing agents. The functional a ...
The metal oxide cluster alpha-AIW(11)O(39)(9-) (1), readily imaged by cryogenic transmission electron microscopy (cryo-TEM), is used as a diagnostic protecting anion to investigate the self-assembly of alkanethiolate monolayers on electrostatically stabili ...
The authors report the prepn. of soln.-derived metal oxide nanocomposite films by combining polyoxometalates (POMs) and colloidal oxide nanocrystals. Polyniobates and vanadates were combined with Sn-doped In2O3 (ITO) nanocrystals leading to Nb2O5-ITO, V2O5 ...