Guanidinium can both Cause and Prevent the Hydrophobic Collapse of Biomacromolecules
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The three-component reaction of aryl boronic acids with 1,2,4,5-tetrahydroxybenzene and 1,2-bis(4-pyridyl)ethylene or 4,4-bipyridine leads to the formation of dark-purple boronate ester polymers. Crystallographic analyses show that the polymer strands have ...
Carrier-mediated drug delivery has emerged as a powerful methodology for the treatment of various pathologies. The therapeutic index of traditional and novel drugs is enhanced via the increase of specificity due to targeting of drugs to a particular tissue ...
Stimuli-responsive polymers have the unique property of undergoing a reversible phase transition. This property has attracted much interest for their application in the field of medicine and biotechnology, such as drug delivery systems. Linear polymers of ...
This thesis is devoted to the study of the dispersion polymerization of methyl methacrylate in supercritical carbon dioxide (scCO2), using a poly(dimethylsiloxane) macromonomer (PDMS macromonomer) as stabilizer. Supercritical fluids (SCF) and SCF mixtures ...
A model showing the importance of the parameters characterizing ion transport through geometrically defined nanoslits filled with electrolyte is presented. A conductance plateau sin log-log scaled at low salt concentrations in the nanometer-sized apertures ...
A linear water-soluble quaternary ammonium polymer having a homopolymeric chain of repeating unit of general formula (I):where each of R1 and R2 independently represents a member selected from the group consisting of linear or branched alkyl, hydroxyalkyl, ...
The dynamics of star polymers is investigated via extensive molecular and Brownian dynamics simulations for a large range of functionality f and packing fraction η. The calculated isodiffusivity curves display both minima and maxima as a function of $ ...
As the need for lower mol. wt. acrylates for specialty and molding applications increases, industry is looking for substitute prodn. processes. An alternative to the increasing of initiator and chain transfer agent concn. is working at higher temps. Howeve ...
L'émergence de procédés de gravure profonde performants (vitesse, anisotropie, uniformité…) de matériaux tels que le silicium (Si), la silice (SiO2) et certains polymères repose sur: • Le développement d'équipement de gravure permettant le contrôle indépen ...
This paper presents a fabrication of polymer microchips with homogeneous material technique due to surface treatment by plasma before sealing. UV laser photoablation was used for fast prototyping of microstructures, and oxygen plasma was used as a surface ...