Quantum State–Resolved Studies of Chemisorption Reactions
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The present work deals with two subjects. The interaction of NO2 and HONO with different types of soot are examined in the first part whereas in the second part an experimental set-up is presented which has been built in order to measure the kinetics of th ...
A low pressure reactor (Knudsen cell) coupled to molecular beam modulated mass spectrometry was used to study the heterogeneous kinetics of the following three systems: (1) NO2 on amorphous carbon, (2) H2O vapor on ice and (3) gaseous HCl on ice. The first ...
The kinetics of surface processes during the growth of GaN by molecular-beam epitaxy (MBE) with ammonia as the source of reactive nitrogen is studied theoretically and experimentally. A model of surface processes is developed taking into account specific e ...
The recent development of temperature controlled scanning tunneling microscopy opened the door to a fascinating new world on the nanometer scale. The atomic scale information obtained provides unprecedented insight into the kinetics of surface phenomena su ...
The first part of this laboratory study deals with heterogeneous reactions of bromine- and chlorine-containing species relevant to the atmosphere with solid model alkali salt substrates. The second part of this work treats the heterogeneous interaction of ...
We describe a new apparatus that combines pulsed laser excitation in a molecular beam with surface-science methods for preparation of clean single-crystal surfaces and detection of adsorbates to enable state-selected studies of gas-surface reaction dynamic ...
We report on long-range interactions between adsorbates on metal surfaces with a surface state. A comparison of three adsorbate/substrate systems [Cu/Cu(111), Co/Cu(111), and Co/Ag(111)] suggests the general existence of such interactions and shows up comm ...
The development of the interfacial bond strength as a function of bonding conditions has been investigated in two representative semicrystalline thermoplastics, isotactic polypropylene and polyamide 12. If one side of the interface is well above the meltin ...
Bromine contg. compds. are thought to play an important role in the O3 destruction in various regions of the atm. Recent studies of atm. Br chem. suggest that HOBr is one of the important Br compds. The rapid photolysis of HOBr in daytime releases Br atoms ...
The aim of this study is to identify the reaction mechanism of methanol dehydrogenation on sodium carbonate catalyst. Quantitative analyses of the products of methanol dehydrogenation on sodium carbonate catalyst at 963 K indicate that methane is formed in ...
