Versatile palladium-catalyzed double carbonylation of aryl bromides

Paul Joseph Dyson, Gabor Laurenczy, Xinbang Wu, Cornel Fink
2017
Article

Résumé

A versatile palladium-catalyzed double carbonylation of aryl bromides has been developed. Using Pd(OAc)2/BuPAd2 as the catalyst system and DBU as the base, under relatively low CO pressure, various a-ketoamides were produced in good yields. In order to get insight into the reaction pathway, real time NMR studies were performed as well and a correlated reaction mechanism is been given.

Source officielle

https://infoscience.epfl.ch/record/232398?ln=fr

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Versatile palladium-catalyzed double carbonylation of aryl bromides

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