Slow CH3NH3+ Diffusion in CH3NH3PbI3 under Light Measured by Solid-State NMR and Tracer Diffusion
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Developments towards an understanding of the nature of conductance at the interface between two different metallic layers – ferromagnetic and non magnetic – as well as the discovery of giant magnetoresistance have stirred attention from both the scientific ...
The phenomenon of magnetism is one of the key components of today's technological progress. Magnetic interactions and magnetic materials are essential for the scientific disciplines of physics, chemistry and biology, making this subject truly multidiscipli ...
The first condensed-phase preparation of ternary P-Ch-X cations (Ch=O-Te, X=F-I) is reported: [P5S3X2]+, [P5S2X2]+, and [P4S4X]+ (X=Br, I). [P5S3X2]+ is formed from the reaction of the Ag+/PX3 reagent with P4S3. The [P5S3X2]+ ions have a structure that is ...
Coherent and dissipative phenomena induced by transient adsorption of xenon-131 on a glass surface were studied by NMR spectroscopy. The authors report the results of multiple-quantum filtered expts. over a range of temps., covering different relaxation re ...
New experiments are described for the determination of very slow diffusion constants by nuclear magnetic resonance (NMR) using long-lived (singlet) states. These experiments are suitable for molecules or conformations featuring a wide range of J-couplings. ...
Adiabaticity plays a central role in modern magnetic resonance experiments, as excitations with adiabatic Hamiltonians allow precise control of the dynamics of the spin states during the course of an experiment. Surprisingly, many commonly used adiabatic p ...
The relaxivity of commercially available gadolinium (Gd)-based contrast agents was studied for X-nuclei resonances with long intrinsic relaxation times ranging from 6 s to several hundred seconds. Omniscan in pure 13C formic acid had a relaxivity of 2.9 mM ...
We present a simple framework for determining the parameters for efficient adiabatic pulses in solids with very large shift anisotropies under very fast MAS. We introduce the notion of the effective adiabatic quality factor to describe the spin dynamics. W ...
In the short time since its introduction, magnetic resonance imaging (MRI) has rapidly evolved to become an indispensable tool for clinical diagnosis and biomedical research. Recently, this methodology has been successfully used for the acquisition of func ...
The observation of nuclear Overhauser effects (NOEs) between bound water and biol. macromols. such as proteins and nucleic acids can be improved by inverting the water resonance selectively while compensating for radiation damping effects. The efficiency o ...