Hybrid laser 3D microprocessing in glass/polymer micromechanical sensor: towards chemical sensing applications
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Polymethylmethacrylate (PMMA) is used in many applications requiring good optical properties, resistance to ageing and resistance to UV irradiation, in spite of its relatively poor mechanical response to impact loading. In order to extend the range of appl ...
The present PhD thesis deals with the high temperature polymerization of methyl methacrylate in a continuous pilot scale process. The major aim is to investigate the feasibility of a polymerization process for the production of PMMA molding compound at tem ...
The endeavour to develop nanodevices demands for patterning methods in the nanoscale. To bring nanodevices to the market, there is a need for fast, low-cost replication nanopatterning methods. In addition, an increased flexibility of the nanopatterning met ...
Stimuli-responsive polymers have the unique property of undergoing a reversible phase transition. This property has attracted much interest for their application in the field of medicine and biotechnology, such as drug delivery systems. Linear polymers of ...
This thesis is devoted to the study of the dispersion polymerization of methyl methacrylate in supercritical carbon dioxide (scCO2), using a poly(dimethylsiloxane) macromonomer (PDMS macromonomer) as stabilizer. Supercritical fluids (SCF) and SCF mixtures ...
Nanoimprint lithography (NIL) is an emerging patterning technology which shows the capability of fabricating nanostructures on a large scale. It is therefore interesting for low-cost NEMS manufacturing. As schematically shown, a stamp made of single crysta ...
Expts. of Me methacrylate dispersion polymn. are carried out in a reaction calorimeter using PDMS-mMA (methacrylate-terminated polydimethylsiloxane) as surfactant. Different stabilizer concns. from 0 to 10 wt% with respect to monomer have been considered i ...
The invention relates to novel polymer-based microstructures, with outstanding shape accuracy and cost-effective processing. The novel polymers are based on hyperbranched macromolecules and enable remarkable property combination such as reduced shrinkage a ...
A ruthenium meso-tetra[4-(vinylbenzoxy)benzyl]porphyrin catalyst with four polymerizable side chains was synthesized in three steps from commercially available starting materials. The polymerizable side chains allowed the incorporation of this complex in h ...
The influence of the surface morphology of semi-crystalline poly(ethylene terephthalate) (PET) and polyamide 12 (PA12) films on the adhesion and cohesion of thin oxide coatings is analysed, with attention paid to the role of spherulites and processing addi ...