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Metal organic supramolecular chemistry on surfaces has matured to a point where its underlying growth mechanisms are well understood and structures of defined coordination environments of metal atoms can be synthesized in a controlled and reproducible proc ...
The nickel(II) hydride complex [(MeN2N)Ni-H] (2) was synthesized by the reaction of [(MeN2N)Ni-OMe] (6) with Ph2SiH2 and was characterized by NMR and IR spectroscopy as well as X-ray crystallography. 2 was unstable in solution, and it decomposed via two re ...
Butene hydrogenation activity is intimately connected with the occupied and unoccupied electronic states of gold active site. We prepare well-defined Au(III) sites in IRMOF-3 structure, and tuned the metal density-of-states by replacing the substituent gro ...
Cross-coupling reactions of non-activated alkyl halides are potentially useful chemical transformations. At the same time, however, they are challenging due to a series of unproductive side reactions. Recently, significant progress has been made to overcom ...
Transition-metal-catalyzed C-C coupling reactions have been extensively studied in the past three decades. These reactions have become invaluable to fundamental research and industrial applications, because they can be used construct complicated molecules ...
The catalytic hydrocarboxylation of linear alkenes to carboxylic acids using supercritical carbon dioxide as a solvent was studied. High selectivities in acids have been obtained. The best results were achieved when adding a perfluorinated surfactant to th ...
Alkylation of alpha -isocyanoacetamide with alkyl halide in MeCN at 0 DegC in the presence of cesium hydroxide afforded the mono-alkylated product in good to excellent yield. [on SciFinder (R)] ...
Complex of general formula I in which R1, R2 and R3, which may be identical or different, represent separately a linear or branched alkyl radical of 1 to 5 carbon atoms, or, together with the nitrogen atom to which they are attached, a heterocyclic ...
Many low oxidation state transition metal (carbonyl) clusters are salts and are highly soluble in ionic liquids. Since many are also effective catalysts/precatalysts for hydrogenation reactions, we have conducted a catalytic study of these compounds in ion ...
Organophosphorus compounds found applications in varied fields of the organic chemistry: they are particularly present in natural compounds such as the deoxyribonucleic acid (DNA) and in the field of catalysis in which their utility is also proven. Thus, t ...