Probing Molecular Chirality by Orbital-Angular-Momentum-Carrying X-ray Pulses
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The mechanism of chiral induction in an optically pure 1,3-diethynylallene, from the central chiral allene moiety into directly adjacent TCBD chromophores, was confirmed and clarified. Only one low-energy conformer is found in calcns. of the potential ener ...
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The present invention relates to an interferometer for x-rays, in particular hard x-rays, for obtaining quantitative x-ray images from an object, comprising: a) an x-ray source, preferably a standard polychromatic x-ray source, b) a diffractive beam splitt ...
A new spin on C60: Axially chiral, pushpull buta-1,3-diene chromophores conjugated to vicinally methylated fullerenes (see picture) have high barriers of rotation about their chiral axes. These high barriers allowed their optical resolution and the determi ...
The diastereoselective synthesis of chiral coordination compounds with d metals proved the effectiveness of the pinene-bipyridine approach in predetermining the chirality at the metal centre. The strong Lewis acidic character of lanthanide cations required ...
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