Time- and Angle-Resolved Photoelectron Spectroscopy of Solar Materials
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The present work deals with the defect chemistry and charge transport properties in halide perovskites, and in particular in the archetypal methylammonium lead iodide. These materials are extensively researched due to their very promising application as li ...
Organic inorganic metal halide perovskites (OIHPs) has emerged as promising photovoltaic materials the latest years. Many OIHPs, however, have complex material compositions with mixed cation and halide compositions, phase mixtures, as well as beneficial re ...
In modern ultrafast optoelectronic technologies based on wide band gap insulators, the non-equilibrium dynamics of photogenerated charges plays a major role. Unravelling the mechanisms of interaction between these charge carriers and their environment is c ...
Undoubtedly, perovskite solar cells have become a key player in 3rd generation photovoltaics over the last few years. Although it is only in 2012 that the first solid state perovskite solar cell was reported, power conversion efficiencies have increased so ...
Transition metal dichalcogenides (TMDs), whether in bulk or in monolayer form, exhibit a rich variety of charge-density-wave (CDW) phases and stronger periodic lattice distortions. While the actual role of nesting has been under debate, it is well understo ...
This thesis investigates the photoinduced charge carrier dynamics of TiO2 nanoparticles and CsPbX3 (X = Cl, Br) nanocrystals, by means of ultrafast x-ray absorption spectroscopy (XAS) and transient absorption spectroscopy (TAS). TiO2 is among the most prom ...
In recent years, semiconductor nanowires have attracted considerable attention as a result of their unique properties and potential applications in many fields. In particular, they can be very attractive materials for certain optoelectronic and electronic ...
EPFL2017
The transition metal oxides are known for their versatile physical properties and are therefore an active field of research towards possible new functionalities and applications. This thesis focuses on the subgroup of titanates with perovskite structure th ...
EPFL2017
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We investigate the metallic surface state in ultrathin films of BaTiO3 by angle-resolved photoemission spectroscopy. We find Fermi-surface contours derived from the Ti 3d t(2g) conduction band, similar as in SrTiO3 but with broader spectral features due to ...
Multinary metal oxides and their heterostructures play a key role as light absorbers in the production of solar chemicals. Synthetic tunability is crucial to understand the impact of composition and structure on the photoelectrochemical performance. Here, ...