Publication

Tuning the Size and Geometry of Heteroleptic Coordination Cages by Varying the Ligand Bent Angle

Publications associées (39)

Nanogels with Metal‐Organic Cages as Functional Crosslinks

A dinuclear metal-organic cage with four acrylate side chains was prepared by self-assembly. Precipitation polymerization of the cage with N-isopropylacrylamide yielded a thermoresponsive nanogel. The host properties of the cage were retained within the ge ...

2024

The acid-mediated isomerization of iridium(iii) complexes with cyclometalated NHC ligands: kinetic vs. thermodynamic control

Kay Severin, Farzaneh Fadaei Tirani, Anastasia Gitlina

The isomerization of iridium(III) complexes with metalated N-heterocyclic carbene (NHC) ligands was studied. The fac isomers of complexes with 1-phenyl-3-methylbenzimidazolin-2-ylidene or 1-phenyl-3-benzylbenzimidazolin-2-ylidene ligands are transformed cl ...

2023

Conjugate heat transfer in isolated granular clusters with interstitial fluid using lattice Boltzmann method

Mehrdad Kiani Oshtorjani

The conjugate heat transfer in mixtures of a fluid and single granular clusters is studied in this paper using a novel lattice Boltzmann method (LBM) programmed for parallel computation on the graphics processing unit (GPU). The LBM is validated for heat c ...

PERGAMON-ELSEVIER SCIENCE LTD2022

Structural elucidation and antibacterial activity of new dialkylstannyl- and chlorodialkylstannyl(IV) 3,4-dihydroisoquinoline-2-(1H)-carbodithioate

In extension with growing concern to develop new antimicrobial organometallic drugs, an attempt has been made to synthesize five new antimicrobial organotin(IV) carbodithioates with general formula, Me2SnClL (1), Me2SnL2 (2), Et2SnClL (3), Et2SnL2 (4), Bu2 ...

ELSEVIER2021

Design and fabrication of piezoelectric coupled MEMS resonators

Jialiang Fan

Multilayer MEMS resonators with physical constraints (coupling beams) were designed, fabricated and characterized, including cantilevers and clamped-clamped beams. This project focused on how the resonance frequencies and coupling constant depend on the ge ...

2020

Seamless integration of design and Kirchhoff-Love shell analysis using analysis-suitable unstructured T-splines

Xiaodong Wei, Deepesh Toshniwal

Analysis-suitable T-splines (ASTS) including both extraordinary points and T-junctions are used to solve Kirchhoff-Love shell problems. Extraordinary points are required to represent surfaces with arbitrary topological genus. T-junctions enable local refin ...

ELSEVIER SCIENCE SA2020

Molecular nanostructures based on polyfunctional clathrochelate complexes

Suzanne Maria Jansze

This thesis describes the design and synthesis of clathrochelate metalloligands for the construction of molecular nanostructures. The low synthetic effort, versatility and stability of the clathrochelate metalloligands makes them particularly suited to the ...

EPFL2019

Engineered nanostructures' characterization by spectral interferometric microscopy

Toralf Scharf, Michail Symeonidis

We characterize engineered nanostructures with sizes smaller than half a wavelength using spectrally resolved interferometry. We analyze the response of the meta-atom of interest, which has a raspberry-like geometry. To identify the origin of the response, ...

SPIE-INT SOC OPTICAL ENGINEERING2019

Restoration of ancient Chinese opera spiral wooden domes, accounts of field practice

Corentin Jean Dominique Fivet, Jingxian Ye

The zaojing is a wooden construction system that covers opera stages for rain protection and sound control. Zaojings in China display a diverse range of geometric expressions, delicate manufacturing, structural behaviours, and acoustic qualities. Despite t ...

ICOMOS2019

In recent years, new methods have been developed to synthesize complex porous and micro-structured geometry in a variety of ways. In this work, we take these approaches one step further and present these methods as an efficacious design paradigm. Specifica ...

2019

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