Stabilizing Unusual Oxidation States of Lanthanides in Molecular Complexes: Synthesis, Properties, and Reactivity
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American Association for the Advancement of Science2001
The electron-releasing ability of certain carbonyls is exploited in the chemistry of the ''naked sugars'' which allows the stereoselective synthesis of rare sugars, C-nucleosides, C-glycosides and a variety of disaccharide mimetics. ...
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The isolation and characterization of Ln(NO3)3 complexes (Ln=La, Pr, Nd, Eu, Tb, Lu) with 2,3-benzo-1,4,7,13-tetraoxa-10-azacyclo-penta-decane (L1) and two of its N-substituted derivatives (L2, L3) are reported. Structural information in the solid state is ...
