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The evolution of triphenylamine hole transport materials for efficient perovskite solar cells

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Molecular Engineering of Fluorene-Based Hole-Transporting Materials for Efficient Perovskite Solar Cells

Mohammad Khaja Nazeeruddin, Hiroyuki Kanda, Albertus Adrian Sutanto, Nadja Isabelle Desiree Klipfel

New Spiro-OMeTAD analogues and the simpler "half" structures with the terminated methoxyphenyl and/or carbazolyl chromophores are successfully synthesized under Hartwig-Buchwald amination conditions using commercially available starting materials. New fluo ...

WILEY-V C H VERLAG GMBH2022

Molecular Electronic Study of Spiro-[cyclopenta[1,2-b:5,4-b ']dithiophene-4,9 '-fluorene] Derivatives: Route to Decent Hole-Transporting Materials

Mohammad Khaja Nazeeruddin, Peng Gao, Michael Saliba, Wei Li

Spiro-type molecules have been extensively explored as hole-transporting materials (HTMs) in perovskite solar cells (PSCs). However, a closer look at the rule of design of such molecules is missing, and a combined experimental and theoretical study is need ...

AMER CHEMICAL SOC2022

Modulating the Electron Transporting Properties of Subphthalocyanines for Inverted Perovskite Solar Cells

Mohammad Khaja Nazeeruddin, Hiroyuki Kanda, Pavel Culik

The lack of organic non-fullerene ETMs with good electron transport and device stability is an important problem for the further development and commercialization of perovskite solar cells. Herein, the use of SubPcs as ETMs in PSCs is explored. To this end ...

FRONTIERS MEDIA SA2022

Hole transport material, synthesis thereof, and solar cell

Michael Graetzel, Shaik Mohammed Zakeeruddin, Yuhang Liu, Michael Bauer

The organic small molecule 4,4',4",4"'-(5,5-dimethoxycyclopenta-1,3-diene-1,2,3,4-tetrayl)tetrakis(N,N-bis(4-methoxyhenyl)aniline (CPDA 1), shows electrochemical properties very close to spiro-OMeTAD indicating a high compatibility with PSC systems for its ...

2022

An Acetylene-Linked 9,9 '-Bicarbazole-Based Hole-Transporting Material for Efficient Perovskite Solar Cells

Jianxing Xia

A new hole-transporting material (XJ-05) based on a 9,9'-bicarbazole core and four acetylene-linked triphenylamine groups was designed and applied for perovskite solar cells (PSCs). Optical spectra, thermal stability, electrochemical properties, density fu ...

AMER CHEMICAL SOC2022

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Although the published values of power conversion efficiency (PCE) have increased continuously in recent years for perovskite solar cells (PSCs), improvements in the stability and performance of PSCs with conventional TiO2 or SnO2 electron transport layers ...

AMER CHEMICAL SOC2022

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Additive engineering is an effective strategy for defect passivation and performance improvement of perovskite solar cells (PSCs). However, few additives have achieved outstanding stability with high efficiency by simultaneously passivating deep and shallo ...

ROYAL SOC CHEMISTRY2022

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In this study, a series of donor-acceptor-donor (D-A-D) type small molecules based on the fluorene and diphenylethenyl enamine units, which are distinguished by different acceptors, as holetransporting materials (HTMs) for perovskite solar cells is present ...

WILEY-V C H VERLAG GMBH2022

Photonic nanostructures mimicking floral epidermis for perovskite solar cells

Mohammad Khaja Nazeeruddin, Hobeom Kim

Here, we report photonic nanostructures replicated from the adaxial epidermis of flower petals onto light-polymerized coatings using low-cost nanoimprint lithography at ambient temperature. These multifunctional nanocoatings are applied to confer enhanced ...

ELSEVIER2022

Dopant-free hole-transporting materials (HTMs) and interface modification are two effective approaches for developing sustainable perovskite solar cells (PSCs). In this work, dopant-free HTM (GW-4) containing an N- ethyl-carbazole with two rotatable vinyl ...

ELSEVIER SCIENCE SA2022