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Symmetry-Induced Singlet-Triplet Inversions in Non-Alternant Hydrocarbons

Publications associées (43)

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Influence of Subsurface Layers on the Adsorption of Large Organic Molecules on Close-Packed Metal Surfaces

Klaus Kern

The asymmetric molecule 4-[trans-2-(pyrid-4-yl-vinyl)] benzoic acid (PVBA) adsorbed on Cu(111) is characterized by scanning tunneling microscopy (STM) and density functional theory (DFT) to determine the influence of subsurface atomic layers on the adsorpt ...

2011

The Benary cross is a classical demonstration showing that the perceived brightness of an area is not solely determined by its luminance, but also by the context in which it is embedded. Despite the fact that two identical grey triangles are flanked by an ...

Pion2011

By measuring the THz electron spin resonance (ESR) transmission spectra and high-field magnetization on the spin-gapped system CuTe2O5, we identified the singlet-triplet excitations in the dimerized non-magnetic ground state. The determined spin-gap value ...

2011

Vibrational Relaxation and Intersystem Crossing of Binuclear Metal Complexes in Solution

Majed Chergui, Frank van Mourik, Andrea Cannizzo, Renske Marjan van der Veen

The ultrafast vibrational-electronic relaxation upon excitation into the singlet (1)A(2u) (d sigma*-> p sigma) excited state of the d(8)-d(8) binuclear complex Pt-2(P2O5H2)(4) has been investigated in different solvents by femtosecond polychromatic f ...

2011

The space-group symmetry of a crystal structure imposes a point-group symmetry on its diffraction pattern, giving rise to so-called symmetry-equivalent reflections. Instances in macromolecular crystallography are discussed in which the symmetry in reciproc ...

International Union of Crystallography2010

A general formalism for the maximal symmetrization and reduction of fields (MSRFs) is proposed and applied to wave functions in solid-state nanostructures. Its primary target is to provide an essential tool for the study and analysis of the electronic and ...

2010

Dislocations are known for their peculiar effects on the diffraction profiles. Each given dislocation type, produces specific anisotropic line broadening basically determined by the so-called contrast factor (CF). Owing to the lack of a suitable mathematic ...

2009

Triplet State Imaging

Dimitri Nestor Alice Van De Ville, Theo Lasser, Boris Hinz, Iwan Märki, Thiemo Spielmann, Aurélie Formey de Saint Louvent

We present a functional imaging method based on triplet state kinetics. The triplet state of many known fluorophores shows a triplet lifetime typically in the order of ~10e-6 – 10e-3 s, 3-6 orders of magnitude longer than the associated fluorescence single ...

2009

Vibrational coherences and relaxation in the high-spin state of aqueous [Fell(bpy)3]2+

Majed Chergui, Frank van Mourik, Andrea Cannizzo, Amal El Nahhas, Cristina Consani, Mirabelle Prémont-Schwarz

Dizzy cooling: Femtosecond excitation of the singlet states of aqueous [FeII(bpy)3]2+ (bpy=2,2-bipyridine) leads to the formation of a vibrationally hot quintet state that exhibits wave-packet dynamics arising from a chelate-ring and bending mode. The vibr ...

2009

Triplet Imaging by Modulated Excitation

Dimitri Nestor Alice Van De Ville, Theo Lasser, Kai Johnsson, Boris Hinz, Thiemo Spielmann, Aurélie Formey de Saint Louvent

We present a functional imaging method based on triplet state kinetics. The triplet state of many known fluorophores show a triplet lifetime typically in the order of ~10e-6 – 10e-3 s, 3-6 orders of magnitude longer than the associated fluorescence singlet ...

2008