A five-stranded heterometallic helicate

Kay Severin, Farzaneh Fadaei Tirani, Sylvain Alexandre Marie Sudan
2023
Article

Résumé

A penta-stranded helicate was obtained by combining Pd(CH3CN)42 with La(NO3)3 and a polydentate ligand. The helicate displays low symmetry, both in solution and in the solid state. A dynamic interconversion between the penta-stranded helicate and a symmetrical, four-stranded helicate was achieved by adjustment of the metal-to-ligand rati

Source officielle

https://infoscience.epfl.ch/record/302986?ln=fr

À propos de ce résultat

Cette page est générée automatiquement et peut contenir des informations qui ne sont pas correctes, complètes, à jour ou pertinentes par rapport à votre recherche. Il en va de même pour toutes les autres pages de ce site. Veillez à vérifier les informations auprès des sources officielles de l'EPFL.

A five-stranded heterometallic helicate

Palladium-based supramolecular assemblies: from complex structures to water-soluble anion-receptors

Steric and Electronic Effects Responsible for N,O- or N,N-Chelating Coordination of Pyrazolones Containing a Pyridine Ring in Ruthenium Arene Systems

Electro- and photochemical H-2 generation by Co(ii) polypyridyl-based catalysts bearing ortho-substituted pyridines

Electro- and photochemical H-2 generation by Co(ii) polypyridyl-based catalysts bearing ortho-substituted pyridines

Palladium-based supramolecular assemblies: from complex structures to water-soluble anion-receptors

Steric and Electronic Effects Responsible for N,O- or N,N-Chelating Coordination of Pyrazolones Containing a Pyridine Ring in Ruthenium Arene Systems