Êtes-vous un étudiant de l'EPFL à la recherche d'un projet de semestre?
Travaillez avec nous sur des projets en science des données et en visualisation, et déployez votre projet sous forme d'application sur Graph Search.
We report on deep-to-near-UV transient absorption spectra of core-shell Au/SiO2 and Au/TiO2 nanoparticles (NPs) excited at the surface plasmon resonance of the Au core, and of UV-excited bare anatase TiO2 NPs. The bleaching of the first excitonic transition of anatase TiO2 at -3.8 eV is a signature of the presence of electrons/ holes in the conduction band (CB)/valence band (VB) of the material. We find that while in bare anatase TiO2 NPs, two-photon excitation does not occur up to the highest used fluences (1.34 mJ/cm2), it takes place in the TiO2 shell at moderate fluences (0.18 mJ/cm2) in Au/TiO2 core-shell NPs, as a result of an enhancement due to the plasmon resonance. We estimate the enhancement factor to be of the order of -108-109. Remarkably, we observe that the bleach of the 3.8 eV band of TiO2 lives significantly longer than in bare TiO2, suggesting that the excess electrons/holes in the conduction/valence band are stored longer in this material.& COPY; 2023 Chinese Laser Press
Giulia Tagliabue, Fateme Kiani Shahvandi, Alan Richard Bowman, Theodoros Tsoulos
Giulia Tagliabue, Fateme Kiani Shahvandi, Alan Richard Bowman, Theodoros Tsoulos