Publication
Synthesis of Fluorescent Cyclic Peptides via Gold(I)-Catalyzed Macrocyclization
Publications associées (32)
Revisiting the concept of extents for chemical reaction systems using an enthalpy balance
Dominique Bonvin, Diogo Filipe Mateus Rodrigues
For the investigation of complex reaction systems, it has been proposed to decouple the various rate processes using a linear time-invariant transformation that is constructed from knowledge of stoichiometry, reaction enthalpies, inlet compositions and tem ...
PERGAMON-ELSEVIER SCIENCE LTD2020Micropollutant Oxidation Studied by Quantum Chemical Computations: Methodology and Applications to Thermodynamics, Kinetics, and Reaction Mechanisms
Urs von Gunten, Minju Lee, Peter Rudolf Tentscher
The abatement of organic micropollutants during oxidation processes has become an emerging issue for various urban water systems such as drinking water, wastewater, and water reuse. Reaction kinetics and mechanisms play an important role in terms of effici ...
AMER CHEMICAL SOC2019Investigation of the heterogeneously catalysed gas phase CO2 hydrogenation reaction: Development of analysis methods and reaction analysis on pristine metal catalysts
Robin Tobias Andreas Mutschler
The aim of this thesis is to contribute to the development of analysis methods that enable an improved investigation of the CO2 hydrogenation reaction such as quantitative mass spectrometry and infrared thermography. Furthermore, the contribution is in the ...
EPFL2019Mechanism and Kinetics of Propane Dehydrogenation and Cracking over Ga/H-MFI Prepared via Vapor-Phase Exchange of H-MFI with GaCI3
In this study, the mechanism and kinetics of C3H8 dehydrogenation and cracking are examined over Ga/H-MFI catalysts prepared via vapor-phase exchange of H-MFI with GaCl3. The present study demonstrates that GaH cations are the active centers for C3H8 ...
2019Real-Time Imaging and Quantification of Peptide Uptake in Vitro and in Vivo
Elena Goun, Hacer Karatas, Aleksey Yevtodiyenko, Tamara Maric, Pier Luca D'Alessandro
Peptides constitute an important class of drugs for the treatment of multiple metabolic, ontological, and neurodegenerative diseases, and several hundred novel therapeutic peptides are currently in the preclinical and clinical stages of development. Howeve ...
AMER CHEMICAL SOC2019Fast real time and quantitative gas analysis method for the investigation of the CO2 reduction reaction mechanism
Andreas Züttel, Emanuele Moioli, Wen Luo, Robin Tobias Andreas Mutschler
We present a new fast real time and quantitative gas analysis method by means of mass spectrometry (MS), which has approximately an order of magnitude faster sampling rate in comparison with a traditional gas chromatography. The method is presented and dis ...
AMER INST PHYSICS2018On decoupling rate processes in chemical reaction systems - Methods and applications
Dominique Bonvin, Julien Léo Billeter, Michael Amrhein, Diogo Filipe Mateus Rodrigues
Models of chemical reaction systems can be complex as they need to include information regarding the reactions and the mass and heat transfers. The commonly used state variables, namely, concentrations and temperatures, express the interplay between many p ...
2018Generalized Incremental Model Identification for Chemical Reaction Systems
Dominique Bonvin, Julien Léo Billeter, Diogo Filipe Mateus Rodrigues, Adrien Oulevey
Identification of kinetic models and estimation of kinetic parameters in chemical reaction systems can be done using Incremental Model Identification (IMI). By using IMI, it is possible to separate the effect of the different reactions and thus investigate ...
2017Incremental Kinetic Modeling of Spectroscopic Data using a Reduced Calibration Model
Dominique Bonvin, Julien Léo Billeter
The identification of kinetic models is an important step for the monitoring, control and optimization of chemical processes. Kinetic models are often based on first principles that describe the evolution of concentrations by means of conservation and cons ...
2017A computer-based prediction platform for the reaction of ozone with organic compounds in aqueous solution: kinetics and mechanisms
Urs von Gunten, Minju Lee, Kathrin Fenner
Ozonation of secondary wastewater effluents can reduce the discharge of micropollutants by transforming their chemical structures. Therefore, a better understanding of the formation of transformation products during ozonation is important. In this study, a ...
Royal Soc Chemistry2017