Local vs. cooperative: Unraveling glass transition mechanisms with SEER
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The connection of twelve peripheral and divergent dodecyloxy chains to a central tridentate aromatic binding unit provides the dodecacatenar ligand L11, for which room- temperature mesomorphism is detected. An enthalpically unbalanced large melting entropy ...
Strontium barium niobate (SrxBa1-xNb2O6, shortly SBN) is a solid solution system with tetragonal tungsten bronze crystal structure. It exhibits a ferroelectric phase with only one polar axis and a transition temperature depending on the Sr/Ba ratio. This t ...
The transport properties of an ionic model for liquid silica [1] at high temperatures and pressure are investigated using molecular dynamics simulations. With increasing pressure, a clear change from "strong" to "fragile" behaviour (according to Angell's c ...
Granular matter submitted to external perturbations exhibits various behaviors depending on the vibration intensity: when strongly vibrated, the granular system has a fluid aspect, whereas under low intensity perturbations, it is in a quasi-solid phase. In ...
This work describes the synthesis as well as the photophysical and mesomorphic properties of new luminescent liquid crystals able to emit narrow bands in the visible range, and featuring lanthanide ions incorporated into pro-mesogenic coronands. In order t ...
Molecular-dynamics simulations are presented for two correlation functions formed with the partial density fluctuations of binary hard-sphere mixtures in order to explore the effects of mixing on the evolution of glassy dynamics upon compressing the liquid ...
Time-resolved Optical Kerr Effect (OKE) measurements were used to det. the orientational dynamics of water and acetonitrile in the bulk and in pores of ZrO2 nanostructured films. The expts. were performed with a home-built OKE microscope, capable of provid ...
The present paper proposes a Monte Carlo model to simulate the evolution of the microstructure during liquid phase sintering. The model mainly assumes that the system temperature is constant and that the composition of the liquid phase is completely homoge ...
PROBLEM TO BE SOLVED: To provide a microchip made of a resin with a microchannel with a channel sealed by an upper substrate which is transparent and absorbs little in ultraviolet region, is minute and has satisfactory surface smoothness, and is high in di ...
The ionic liquid 1-dodecyl-3-methylimidazole chloride ([C12- mim]Cl) is doped with 1 mol-% of the lanthanide ternary complexes [Ln(tta)3(phen)] (tta = thenoyltrifluoroacetonate, phen = 1,10-phenanthroline, Ln = Nd, Eu, Er, Yb), resulting in luminescent mes ...
