Endeavors in synthetically oriented organometallic chemistry
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Researchers have argued that specialization within groups yields productivity gains. We evaluate this statement with a focus on groups of Ph.D. students. Using an established technique in computer science called Latent Dirichlet Allocation, we construct a ...
Institute of Electrical and Electronics Engineers2014
Alkynes are used as building blocks in synthetic and medicinal chemistry, chemical biology, and materials science. Therefore, efficient methods for their synthesis are the subject of intensive research. Herein, we report the direct synthesis of alkynes fro ...
Alkynes are among the most versatile functional groups in organic synthesis. They are also frequently used in chemical biology and materials science. Whereas alkynes are traditionally added as nucleophiles into organic molecules, hypervalent iodine reagent ...
We review the research done in recent years in our group on the effects of nanostructure symmetry, and outline its relevance both for nanostructure physics and for computations of their electronic and optical properties. The exemples of C3v and C2v quantum ...
We investigate Farley’s CAT(0) cubical model for Thompson’s group F (we adopt the classical language of F, using binary trees and piecewise linear maps, avoiding the one of diagram groups and pictures). Main results include: in general, Thompson’s group el ...
We prove that amenability of a discrete group is equivalent to dimension flatness of certain ring inclusions naturally associated with measure preserving actions of the group. This provides a group-measure space theoretic solution to a conjecture of Luck s ...
The direct and enantioselective functionalization of inert bonds such as carbon-hydrogen and carbon-carbon is an emerging tool towards more sustainable and efficient synthetic methods. The individual activation pathways like concerted deprotonation metalat ...
Carbon-carbon bond forming reactions are among the most important and useful methods for organic synthesis. During the last years, significant progress has been made in this field. Whereas many catalysts were developed for the coupling of aryl, alkenyl, an ...
The integrated approach for the design of solid catalysts for process intensification is presented addressing simultaneously different levels of scale and complexity involved in the development starting from the molecular/nano-scale of the active phase opt ...
Although research and development (R&D) networks influence the innovation performance of their members, firms may not be fully aware of the scope of their network. In particular, due to cost reasons, they may not be fully informed of their “indirect ties”, ...