Hydrogénation sélective du 2-butyne-1,4-diol avec des catalyseurs de palladium supportés sur des matériaux filamenteux structurés
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The Supercritical-Water-Cooled Reactor (SCWR) is the Generation IV reactor concept most closely related to current light water reactors (LWRs). The SCWR builds on the vast experience with today's LWRs and supercritical coal-fired power plants. Water at sup ...
The identification of kinetic models is an essential step for the monitoring, control and optimization of industrial processes. This is particularly true for the chemical and pharmaceutical industries, where the current trend of strong competition calls fo ...
This study aimed at the development of active and stable structured catalyst for the decomposition of hydrogen peroxide under industrial conditions. Sintered metal fibers of stainless steel (SMFss) in the form of flat panels were surface coated by differen ...
Nitrogen-doped and un-doped carbon nanofibers layers, denoted as N-CNFs and CNFs respectively, coating the walls of cordierite monoliths have been used as support for Pd and Ru catalyst. They have been tested in bromate reduction in batch and continuous op ...
This report describes a full study of the gold-catalyzed direct alkynylation of indoles, pyrroles, and thiophenes using alkynyl hypervalent iodine reagents, especially the study of the structural requirements of alkynyl benziodoxolones for an efficient ace ...
Hierarchical zeolites are a class of microporous catalysts and adsorbents that also contain mesopores, which allow for fast transport of bulky molecules and thereby enable improved performance in petrochemical and biomass processing. We used repetitive bra ...
Reaction rate distribution measurements are reported from experiments in an SCWR-like test lattice performed with separated moderator and coolant regions. This work was done at the zero-power research reactor PROTEUS at the Paul Scherrer Institute in Switz ...
Sequential enyne cross-metathesis reactions of arylalkynes with ethylene followed by atom transfer radical addition (ATRA) with ethyl dichloroacetate or dichloroacetonitrile provide 1,5-dichloropent-2-ene derivatives. The second-generation Grubbs alkyliden ...
Bimetallic (Pd-Cu, Pd-Sn) nanoparticles supported on structured fibrous carbons (activated carbon fibers and carbon nanofibers grown on sintered metal fibers) were tested in nitrate removal of natural polluted water by hydrogen (a batch and continuous mode ...
The nickel(II) hydride complex [(MeN2N)Ni-H] (2) was synthesized by the reaction of [(MeN2N)Ni-OMe] (6) with Ph2SiH2 and was characterized by NMR and IR spectroscopy as well as X-ray crystallography. 2 was unstable in solution, and it decomposed via two re ...
