Méthodologie de dimensionnement des zones de protection des captages d'eaux souterraines contre les polluants chimiques persistants

Thierry Bussard
EPFL, 2005
Thèse EPFL

Résumé

This research proposes a general methodology allowing the delimitation of protection areas for abstracted groundwater against persistent chemical contaminants for the setting up of: (1) remediation programmes in the event of contamination and (2) prevention programmes, in a general way. Since such substances are mainly transported by water circulation, this approach suggests delineating protection areas on the basis of the complete groundwater flow cycle, from the surface of the catchment zone to the groundwater source itself. Areas with the highest contribution rate to the groundwater source will be protected first and foremost. The method under consideration is essentially applied to diffuse contaminants, such as pesticides or nitrates released by agriculture. If pollution is local, a standard method must be applied to treat the problem at the root. The methodology proposes the following steps, which start from the groundwater source and are widened, upstream, to the catchment zone: Identifying the aquifer portion that supplies the groundwater source. Defining, on the ground surface, the catchment zone of the groundwater source. Quantifying the recharge and discharge processes. Calculating the contribution to the groundwater abstraction rate of any point i on the catchment zone surface (Ci) by the following equation: Ci = Ii(1-ei)Pi [m/s] Ii : Infiltration of the precipitation or stream losses at point i [m/s]. ei : Discharge coefficient of water before reaching the main groundwater table (agricultural draining, perched water table, etc.), 0 ≤ e ≤ 1 [-]. Pi : Probability of a particle of water that reaches the groundwater table from point i at the surface going to the groundwater source, 0 ≤ P ≤ 1 [-]. Checking the results (water and mass balances). When the results are not satisfactory, the steps will have to be reiterated. Delineating protection areas (areas with the highest C will be primarily protected). With this approach, we propose not to confine ourselves taking the totality of the catchment zone as protection area against persistent contaminants (protection defined in most of the countries), but to define a smaller area of protection by selecting only the most contributive surfaces. As the acreage of the protection area can be considerably reduced, it will be possible to apply more severe regulations to it, which could never be done on the scale of the entire acreage of the catchment zone. Protection areas defined on this basis moreover allow target remediation solutions(1) which optimize the efficiency/cost ratio. They are, by their very concept, independent of the flux of contaminants at any given time and provide a tool for sustainable development and land planning. For each groundwater source, a rapid calculation based on the contribution field can be made to estimate the potential efficiency of the method and determine the remediation surface that is necessary to reduce contamination. In the same way, the effects of the potential development of the region can be evaluated. The contribution isoline that delimits the protection area can be proposed on the basis of this result. Three actual cases have been treated in order to test the method's applicability. The results are convincing in various porous or fractured aquifers. In the three sites, the results show that, with a similar remediation surface, remediation is more efficient when acting according to the concept of the methodology than when operating without spatial differentiation. ---------- (1) This study uses the concept of a "natural" remediation surface whereby contaminant leaching is reduced by a change in cultivation or in proceedings. The conversion of cultivated areas into meadows is, e.g., one of the most effective methods to reduce nitrates leaching.

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https://infoscience.epfl.ch/record/49883?ln=fr

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Thierry Bussard
EPFL, 2005
Thèse EPFL

Résumé

Official source

https://infoscience.epfl.ch/record/49883?ln=fr

À propos de ce résultat

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The effect of seasonal soil frost on the alpine groundwater recharge including climate change aspects

Daniel Bayard

In alpine areas, the snow cover plays an important role as a water reservoir. Water is stored as snow over the winter and released in spring, recharging mountain aquifers through infiltration. These aquifers are essential, especially for supplying water for human activities during dry seasons. Numerous studies have shown that locally soil frost can drastically reduce the water infiltration. However, we know much less about the hydrological impact of soil frost at a larger scale, in particular with regard to groundwater recharge. This was our motivation for initiating an extensive field experiment in the southern Swiss Alps. Several methods at different spatial scales were adapted to explore (a) the local effect of a partially frozen ground on the snowmelt discharge in an alpine area, (b) the key processes influencing groundwater recharge during snowmelt periods, such as snow cover and soil frost evolution, snowmelt water runoff types, (c) the large-scale effect of soil frost on the aquifer recharge, and (d) winter situations that are critical with respect to flooding. In order to take into account spatial, altitudinal and climatic differences, the field study was run for two winter seasons at Gd St Bernard (2500 m), a site with very high winter precipitation and strong winds, and at Hannigalp above Grächen (2100 m), a ski resort with a rather dry winter climate. The different components of the soil water balance (lateral runoff, deep percolation, liquid soil water content) were measured on delimited plots of 5 m2. Additionally, a dye tracer experiment visualized the snowmelt infiltration patterns into the frozen, respectively non-frozen ground. At Gd St Bernard, investigations of the liquid water content and the soil temperature were additionally conducted at two secondary sites, differing in their orientation, so as to gain a better insight of the spatial soil frost expansion. Finally, an analysis of the water-table variation at the village of Grächen (some 500 m below Hannigalp) during the snowmelt was carried out for a 10-year time period, including our experimental seasons. We complemented our field investigations by using a numerical soil-snow-atmosphere transfer model that simulates the seasonal development of the soil frost and the snow cover, as well as lateral and vertical water flow in the top soil. This model was used as an upper boundary condition to a 2-D groundwater model, to calculate the outlet flow at the base of a simplified alpine aquifer. The two winters investigated had contrasting meteorological conditions, which resulted in intriguing differences and similarities with respect to the soil physical conditions: the first one having a thick snowpack and hardly any soil frost, and the second one with hardly any snow until January and a deep and persistent soil frost. In spite of a very thick snowpack, the water balance measurements from winter 2000/2001 showed for both sites zero to low surface and subsurface flow due to the fact that soil frost was local and the soil permeability high. During the next winter, approximately 25% of the total meltwater run off laterally. The soil infiltration capacity was mainly reduced by the presence of a basal ice sheet, caused by the freezing of meltwater after a mid-winter snowmelt event. The field data were used to calibrate and validate a physically-based one-dimensional model. To allow an accurate parameter setting for the water repellent soil of Hannigalp, laboratory infiltration experiments on soil columns were additionally carried out. Using the resultant information, the model predicted correctly most measured soil parameters, in particular good matching was observed between measured and simulated snowmelt discharge. At Gd St Bernard, the simulated results were less satisfactory, especially during the first winter, when large discrepancies were noted between measured and simulated lateral runoff. Apart from the shortage in the soil parameter characterization, the deviation was a result of the simplified description of the experimental field. The model was, for example, not able to simulate surface runoff generated by a steep slope under unfrozen conditions, as the soil surface is considered by the model to be flat. Nevertheless, results were accurate enough to reproduce the occurrences of snowmelt events and the accumulated values of snow-melt discharge pathways under frozen conditions. Long-term weather data were used to simulate the soil frost depth at both sites. The simulation results showed that the probability of the occurrence of frozen soils was lowest on slopes with south or north exposure. On southerly exposed plots, the heat stored in the soil during the summer inhibited the development of deep and persistent soil frost, while most pore ice thawed due to underneath heating. On north plots, the building of soil frost was rare, as early snowfall insulated the ground from the atmosphere. However, during snow-poor winters, the frost penetrated deep into the ground, and the low underneath heat flux at that location hardly affected the frost depth until snowmelt. The snow depth and average soil temperature were hence the two components affecting the frost depth extent. The altitude soil frost variation was related to the spatial extent of these two components. The higher the altitude, the higher the precipitation and the lower the mean air/surface temperature. Simulating the whole Grächen recharge area, seasonal soil frost was rare between 1800 m and 2000 m, as the snowpack was thick enough to insulate the ground, and the soil was warm enough to inhibit deep soil frost. In lower areas, the shallow snowpack enabled the soil to freeze during most winters, whereas at higher areas, deep and persistent soil frost was simulated due to the low underneath heating. A 10-year water-table depth record was used to examine possible large-scale effects of seasonal soil frost. We noted that the water-table rise at snowmelt was lowest at the end of winters with extensive soil frost. However, such winters were characterized by low precipitation, and reduced snow cover. In contrast, winters with little soil frost were mostly snow rich. Consequently, only a reduced number of winters were directly comparable. Considering these winters, the reduction in the water-table rise at snowmelt due to seasonal soil frost varied only between 10 and 30%, as, during snowmelt, most meltwater was able to re-infiltrate into the very permeable ground in lower unfrozen areas. We may assume that a soil with a smaller infiltration capacity can increase the influence of the soil frost on the aquifer recharge. Finally, we investigated the effect of a changing climate on the hydraulic and thermic regimes at different altitudes in the area of Grächen. We assume an increase in the air temperature of 2°C generates deeper soil frost on lower areas, as the resultant smaller snow cover does not insulate the soil from the atmosphere any more. However, it does reduce the soil frost on higher, snow rich areas, due to the warmer air temperature. As a whole, minor changes were simulated on the mean groundwater recharge, as more/less meltwater was able to infiltrate in higher/lower areas. By increasing additionally the precipitation by 15%, the soil frost diminished slightly over the whole catchment. By combining both climate change scenarios, we may expect an increase in extreme events, as, on the one hand, the rainfall intensity increases, and, on the other hand, rain on snow events over frozen soils occurs more often in lower areas. In practice, this work shows the importance of better investigating the hydrothermal behaviour of alpine regions. Such a knowledge is necessary, as more and more efforts are put into managing efficiently, durably and globally the available water resources. This work stresses also the necessity to consider seasonally soil frost in alpine risk management. As an example, flooding is mostly a consequence of strong rain precipitation at high altitudes combined with heavy snowmelt. Obviously, the risk of extreme runoff events increases during frozen winters, when the soil infiltration capacity is further reduced by the soil ice. Also, it has been shown that unstable slopes are mostly related to specific hydrogeological situations, like strong precipitation, which induces a sharp increase in the underneath water circulation. The melt water in spring is hence a potential activating factor, and a frozen soil may reduce the risk of sliding, as less water infiltrates into the ground.

EPFL2003

Chargement

Méthodes d'analyse du fonctionnement hydrogéologique des versants instables

Pierre Tullen

Significant progress was made these last decades in the development of hydrogeological methods. However, these new methods are still very little used in the problematics of unstable slopes, mainly because of the hydrogeological complexity, which characterizes them (thin aquifers, discontinuous media, succession of saturated and unsaturated zones, lower permeability, higher hydraulic gradients, evolution of the permeability in time in relation to slope movements, etc.). Consequently, the approach usually developed to study slope instabilities is based on the setting-up of relations between hydroclimatologic parameters and slope movements. This approach exclusively concentrates on causes and effects, without developing the processes induced by these causes and responsible for these effects. This "black-box" type of relation is in some cases satisfactory, but in others, the analysis of the induced hydrogeological processes becomes essential to understand the functioning of the instability phenomenon and to predict the movements. Our project aims at introducing this missing link to allow a better understanding of the hydrogeological processes caused by particular hydroclimatologic conditions. It is a matter of determining the relation between hydroclimatologic phenomena and a critical hydrogeological state, which can lead a phenomenon of instability to reactivation or to a state of rupture. Unfortunately, this relation cannot be approached in the same way for all instabilities throughout the world. Owing to the specificity of each slope, the relation must be established individually, which may lead to a hydrogeological typology of unstable slopes. Accordingly, we propose a methodology comprising a succession of stages that are useful for the understanding of the hydrogeological processes underlying slopes. This approach aims at establishing a hydrogeological assessment on the scale of the slope or, if necessary, on a regional scale, in order to determine groundwater infiltration zones, trajectory and velocity of groundwater run-off as well as outlet areas. The usual ways of doing this are generally the measurement of the river flow rate, a pluviometric follow-up or direct hydrogeological measurements via piezometers. These traditional approaches generally remain limited by problems of space representativeness or life span; on top of this come problems of cost due to the often chaotic morphology of the slope instabilities and the fact that they are not easily accessible. To make up for these various problems, we propose a complete methodological approach to improve the understanding of the groundwater run-off systems for the unstable slopes: A characterization of the geological domain based on geophysical measurements in addition to the borehole data. This approach, original in the specific context of unstable slopes, makes it possible to obtain a three-dimensional representation of the heterogeneity which composes the subsurface grounds in a fast, efficient and economic way; A spatialization of the climatologic observations in order to take into account the distribution of the precipitations while considering the various states (rain and/or snow) that constitute the water contribution to a slope in relation to altitude; A hydrogeochemical characterization of the outlets, which makes it possible to assess the general groundwater circulation system within the slope, and to come to a decision about one or several possible trajectories of groundwater run-off; An isotopic characterization of the outlets, which allows estimating the altitude of infiltration of the groundwater. This characterization can also give some information on the infiltration zones. These methods also make it possible to characterize the general groundwater run-off system. In some cases, it is also possible to come to a conclusion, quantitatively speaking, concerning the mixing between several reservoirs and to estimate the time of residence of the water in the aquiferous system; A qualitative validation of the assumptions on the basis of artificial tracing tests which will attest the existence of hydrogeological connections between a catchment area and an outlet. This approach will also inform about the time of residence of water; A validation of the conceptual model on the basis of a bi- or three-dimensional numerical simulation of the groundwater run-off in order to validate the hydrological and hydrogeological relations. The calibration of these numerical models is based on a set of hydrogeological data, in particular the outlet discharge, the isotopic composition of water and/or their hydrochemical composition. These strictly hydrogeological numerical simulations can then be translated into a mechanical state to evaluate the stability of the slope. The whole of the points suggested by this methodological approach is not always essential to determine the hydrogeological processes that govern each slope. According to the characteristics of each study site and the means at disposal, some could be treated only partly, or not at all, depending on the established objectives. In the end, a hydrogeological typology of the unstable slopes should make it possible to propose a standard methodological approach and specific tools for analysis in direct relationship to the hydrogeological context which characterizes each slope. The methodological approach suggested in this PhD thesis was tested and validated on three representative sites through Switzerland and the alpine arc that present quite distinct characteristics of hydrogeological functioning. They are the slopes of Hohberg in the canton of Fribourg, Triesenberg in the Principality of Liechtenstein and Peney in the canton of Geneva. This validation phase allowed to assess the hydrogeological functioning of the three studied slopes and to evaluate the relation between the hydrogeological processes and the phenomena of instability. An approach such as that presented in this study opens up prospects to carry out means of sustainable stabilization with an aim of solving problems of slope instabilities.

EPFL2002

Chargement

A new concept of road runoff management, based on diffuse infiltration over the shoulder, was tested in a real-scale experimentation site located near Grandson, Switzerland. This new concept consists in diffusely infiltrating the road runoff in the infiltration slope adjoining the road shoulder; where road contaminants are retained. This presupposed that the road shoulder was as tightened as possible to effectively drive the road runoff to the slope, and that the infiltration slope effectively retains all road pollutants. Those two main postulates needed strong scientific verification. For this purpose, five different shoulder designs were tested in Grandson to assess which one presented the best hydraulic performance, i.e. which shoulder was the most impervious. Those designs were made of gravel mixed with humus (SGL), gravel mixed with clay (SGC), gravel seeded with lawn (SGL), a prolonged HMF road base (SH), and a bentonitic geotextile tightening (SB). Also, to verify the retention of pollutant, two infiltration slopes adjoining SGL (LW) and SH (LH) were set as lysimeter (basal geomembrane collecting road effluents); the third infiltration slope (LB) had a direct connection with the aquifer which was closely monitored (6 piezometers located up- and downstream from the road; influence of the road runoff was thus emphasized). Finally, to ensure that this new concept do not lower the road bearing capacity, deflectometers were placed in the road structure; 3 campaigns of leveling assessed the road settlement. Hydraulic assessment of the shoulders, based on 112 natural precipitation as well as 3 artificial watering tests, showed strong discrepancies between all shoulders behaviours. They had to deal with potentially high amount of water. Lag times ranged from a few minutes to several hours. Results showed that lag times were only function of the precipitation mean intensity. The infiltration process could be assessed by a modified Green & Ampt equation. The moisturizing front was frank and linearly progressed downward. Shoulders vertical hydraulic conductivities ranged from 4.6·10-6 (SGC) to 2.2·10-5 m·s-1 (SGL). The exfiltration volume is function of the water volume available at the shoulder surface. The drought preceding the rain event has no influence on the stock variation or the exfiltration volume. Road runoff used two different infiltration paths: the macroporosity drives the water efficiently and rapidly, while the microporosity is less efficient and retains the moisture longer. Tracer tests (Brine) proved that the contamination first flush passed over the shoulders. This is also confirmed by the flux calculation. Runoff coefficients CR ranged from 0.3 (SGL) to 0.9 (SB). This coefficient decreased rapidly once the shoulder is wet. Only SB really fulfilled its task, letting water through only in harsh hydraulic conditions (100 mm; 40mm/h). It is highly recommended for further road development: for new roads as well as old roads being refurbished. The shoulder SH proved to be inefficient for structural and material reasons. Other shoulders are comparatively ineffective. SGC must be enhanced; in that case it could offer a valuable alternative. The bearing capacity of the road was very good. The road lifetime was evaluated to more than 20 years (1·109 residual standard axle load). The Grandson experimental site could not conclusively demonstrate a worsening of the geotechnical behaviour of the road. This is due to the particularly good material and road pavement thickness used for this road. Infiltrations in shoulders are high enough and would have doubtless caused a loss of bearing capacity in case the road would have been more modestly dimensioned. It is therefore clear that the shoulder must be tightened. Geochemical results concerned six families of contaminant: MTE, PAH, Cx, BTEX, MTBE, and PCB. Batch and column tests allowed calculating MTE and PAH distribution coefficient Kd in the Grandson soils, as well as in other typical Swiss soils. Results showed that mobile elements are B, Br, Mo, Ba, Sb, Zn, and V (0 < Kd < 90). Less mobile elements are Ni, Cd, Cr, and Rb (200 < Kd < 300). Elements with very low mobility are Pb, Mn, and Ti (1500 < Kd < 3500). PAH mobility was high for the light PAH (naphthalene, acenaphtene, fluorene, anthracene; Kd < 75). Heavy PAH had lower mobility (Kd > 175). Comparisons with other typical soils enlightened the predominant influence of the pH. Batch test performed with acidic soils (pH = 5.5) confirmed lower MTE Kd. MTE are thus more mobile in acidic soils. Other physicochemical parameters have a smaller influence. The column test performed with a synthetically loaded solution (MTE and PAH) infiltrating the Grandson soils showed that MTE are more mobile in dynamic conditions. This is easily explained by the reduced contact time between the contaminant and the soil aggregates. PAH were not detected at the column outlet, thus showing a very good retention in the column soil. Soil layers analyses demonstrated that PAH were mostly retained in the surface layers. Also, MTE with low mobility show the same behaviour. Mobile elements showed no preferential retention layer. Concerning the infiltration slope, lag times were usually greater than those encountered for the shoulders. Lag time were function of the rain mean intensity. The influence of the preceding drought was significant. Exfiltration volumes EL were high in case of large event; it could be approximated by a simple equation function of the API and surface available water. Moisture redistribution processes occurred in the soils as long as there is a volumetric water content θ gradient. Fluxes strongly varied in magnitude and direction during a precipitation event: usually from about 1·10-8 to 1·10-5 m·s-1 and from up- to downward (evaporation to infiltration). The first flush effect was poor to medium. NaCl signal was highly buffered. The pH was also completely buffered by the soil high carbonate content. It thus shifted from 6.5 in the rainwater to 8 in the LW exfiltration water. To especially emphasize the geochemical behaviour, an artificial precipitation test was created to control every aspect of the rainfall. It was judged very representative of a natural storm. MTE and PAH contaminants had two different behaviours: mobile elements moved mainly in solute and have concentration correlated with EC. Elements with low mobility had higher concentrations correlated with the turbidity peaks. They were transported sorbed to particles. Comparison between the particular and solute form concentrations confirmed that mobile elements are measured in similar concentrations whether the sample was filtered at 0.45 µm, at 1 µm, or not filtered at all prior to acidification. On the contrary, less mobile elements are easily sorbed to particles. The MTE concentrations under sorbed form range from 5% (Rb, Sb) to 98% (Pb) of the total concentration. They had strong first flush effects. B, V, Cr, Mn, Ni, CU, Zn, Br, Mo, Cd, Sb, and Pb were identified as road tracers. Fe and Al represented 80% of the road runoff. Overall, the total MTE concentration in the lysimeter first water collected decreased to 1/30th of the road runoff first flush concentration. Mobile elements were less retained. The PAH total concentration in the lysimeter first collected water was about 1'000 times lower than in the road runoff first flush. The PAH concentration was mainly constituted by mobile PAH naphthalene and phenanthrene. Cx were well represented in the road runoff. However, only heavy species were commonly found. C32 was the most common specie. The triplet C16-C18-C20 was always present in high concentration in the lysimeter exfiltration water. This triple is a great road tracer. BTEX, while present in the road runoff, were not detected in the lysimeter exfiltration water. The alluvial aquifer was also monitored. It is confined between the Arnon (north) and a basement till which shallows up southward. Eastern and western limit are less known but might coincide with the river. The aquifer is clearly linked to the river. This is proved by the piezometric level, EC and T follow-up. EC and temperature also emphasized the higher activity in downstream piezometer. The road runoff infiltration could not be emphasized by the NaCl tracer test. The infiltrated water concentration was possibly buffered by the aquifer volume. Also, the brine was heavier than the aquifer water: it could have plunged to the bottom of the aquifer. All families of contaminant are presented in the aquifer. However, the provenance of those contaminants remains uncertain. The groundwater was indeed as concentrated upstream as downstream. Moreover, the river concentrations had similar, or even higher, values. The contamination provenance is thus either the aerial deposition (equally distributed up- and downstream), either the Arnon River infiltrating the aquifer. The contaminant behaviours in the aquifer could be described. It confirmed the contaminant mobility previously noted during the batch, column and test precipitation experiments. Mobile substances are seen in higher concentrations, whereas substances with low mobility are sparsely found. This project thus demonstrated that the new "over the shoulder diffuse infiltration" concept is clearly implementable. Aquifer concentrations were compared to Swiss legal concentration limits. Except for Cr, the aquifer water was of drinkable quality. This proved that the concept is robust, environmental-friendly and conclusive.

EPFL2007

Chargement

The effect of seasonal soil frost on the alpine groundwater recharge including climate change aspects

Daniel Bayard

EPFL2003

EPFL2007

Méthodes d'analyse du fonctionnement hydrogéologique des versants instables

Pierre Tullen

EPFL2002