Fluorescent star-shaped polystyrenes: "Core-first" synthesis from perylene-based ATRP initiators and dynamic mechanical solid-state properties
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The present PhD thesis deals with the high temperature polymerization of methyl methacrylate in a continuous pilot scale process. The major aim is to investigate the feasibility of a polymerization process for the production of PMMA molding compound at tem ...
This report describes the aqueous solution self-assembly of a series of polystyrenem-b-poly(L-lysine)n block copolymers (m = 8-10; n = 10-70). The polymers are prepared by ring-opening polymerization of e-benzyloxycarbonyl-L-lysine AT-carboxyanhydride usin ...
This thesis is devoted to the study of the dispersion polymerization of methyl methacrylate in supercritical carbon dioxide (scCO2), using a poly(dimethylsiloxane) macromonomer (PDMS macromonomer) as stabilizer. Supercritical fluids (SCF) and SCF mixtures ...
Stimuli-responsive polymers have the unique property of undergoing a reversible phase transition. This property has attracted much interest for their application in the field of medicine and biotechnology, such as drug delivery systems. Linear polymers of ...
The kinetic properties of the Me methacrylate (MMA) polymn. at pilot scale for a given temp. range (130-170 Deg) were detd. by differential scanning calorimetry and batch expts. reflecting initiation by MMA peroxides, depropagation of the living chains as ...
The structural arrest and the dynamics in star polymer solutions in the presence of attractive forces between microparticles were studied. The effect of the interplay between attractive interactions of different range and ultrasoft core repulsion, on the d ...
The different steps associated with the curing of a PVAc/polyester blend are identified and correlated to the mechanism of shrinkage control in the presence of a low-profile additive (LPA). Poly(vinyl acetate) (PVAc) is used as a LPA and is shown to induce ...
The bimetallic ruthenium complex [(1,3,5-C6H3i-Pr3)Ru(m-Cl)3RuCl(C2H4)(PCy3)] has been synthesized by reaction of [(1,3,5-C6H3i-Pr3)RuCl2)]2 with one equivalent of PCy3 in the presence of ethylene. It can be used as a catalyst precursor for the controlled ...
A review in 4 sections comprising synthetic methods and prodn. processes of plastics (section I), apparatuses for prodn., processing, and making of plastics (section II), manufg. processes for the most important plastics (section III), and processing of th ...
Even unsubstituted butadiene adds to sulfur dioxide in the hetero-Diels-Alder mode more rapidly than in the chelotropic mode. The sultine can be observed in equilibrium with the diene and the sulfur dioxide only at low temperature and in the presence of CF ...
