Several methods to synthesize bimetallic complexes in which two different metal fragments are connected by halide bridges are described. Using simple starting materials a large pool of structurally defined bimetallic complexes with unique chemical reactivities can be prepared in short time. Applications in organometallic synthesis and homogeneous catalysis are discussed.
Matthew Wodrich, Shubhajit Das, Anne-Clémence Corminboeuf, Hanna Hinrika Cramer
Jérôme Waser, Xingyu Liu, Nieves Pilar Ramirez Hernandez, Tobias Michael Milzarek