H-aggregation and correlated absorption and emission of a merocyanine dye in solution, at the surface and in the solid state. A link between crystal structure and photophysical properties
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Crystal clear: After two decades of controversy the elusive skew-boat conformation of L-iduronic acid (see picture) was finally ascertained at atomic resolution in a synthetic, substituted disaccharide. This highly flexible compound crystallizes in two dim ...
Organic semiconductors are promising materials for future electronic and electroluminescence applications. A detailed understanding of organic layers and nano-sized crystals down to single molecules can address fundamental questions of contacting organic s ...
Time resolved optical Kerr effect measurements have been used to det. the orientational dynamics of water in the pores of ZrO2 nanostructured films. We demonstrate that local heating effects can safely be ignored and present our results which are manifestl ...
Experimental work has been done to determine changes in the particle shape of portlandite grown in the presence of different ions. To quantify the experimentally observed changes in morphology a new analysis tool was developed, allowing the calculation of ...
Photocatalytic degradation of phenol, nalidixic acid, mixture of pesticides, and another of emerging contaminants in water was mediated by TiO2 and iron oxide immobilized on functionalized polyvinyl fluoride films (PVFf-TiO2-Fe oxide) in a compound parabol ...
The work presented in this thesis was carried out in the framework of two European projects: SOLWATER, and AQUACAT. The global objective of those projects, including the present work, was to set an autonomous system for drinking water production in develop ...
The commercially available fluorescence dye 8-hydroxypyrene-1,3,6-trisulfonate (HPTS) can be used as a selective molecular probe for the detection of caffeine in aqueous solution. ...
We report exptl. results concerning the STM imaging of cis-bis (isothiocyanate)-bis-(2,2'-bipyridyl-4,4'dicarboxylate)ruthenium(II)bis(tetrabutylammonium) dye (known as N719) adsorbed on a single crystal of anatase TiO2(100). The cleaning pretreatment, by ...
We present a spectral tuning mechanism of photonic crystal microcavities based on microfluidics. The microinfiltration with water of one or few cavity holes and its subsequent controlled evaporation allow us to tune the cavity resonances in a spectral rang ...
The synthesis of bismuth vanadate (BiVO4) nanoparticles has drawn considerable attention to their application as a visible-light-driven photocatalyst. Several techniques are addressing the enlargement of surface area, but some of them can cause impurities ...
