Oxidation of organics by intermediates of water discharge on IrO2 and synthetic diamond anodes
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The electrochem. oxidn. of 3-methylpyridine (3-MP) at synthetic boron-doped diamond (BDD) thin film electrode was studied in acid media by cyclic voltammetry and bulk electrolysis. The results showed that in the potential region of water stability there ca ...
The electrochem. oxidns. of some org. compds. have shown that only reactions involving simple electron transfer are active on diamond electrodes in the potential region of water stability. For more complex reactions, diamond electrodes show no electrocatal ...
The electrochem. behavior of some model org. compds. on boron-doped synthetic diamond thin film electrodes, obtained by HF-CVD on p-Si substrate was investigated. Only reactions involving simple electron transfer like hydroquinone/benzoquinone are active i ...
Recent progress made in our lab. in the field of electrochem. promotion of heterogeneous catalytic gas reactions is reviewed. The phenomenon consists of electrochem. polarization of the catalyst/solid electrolyte interface resulting in a dramatic, non-Fara ...
The electrochemical promotion of heterogeneous catalytic reactions is a new development which draws the attention of the scientific community as much to fundamental research as to the possible direct applications of this phenomenon in automotive and in ind ...
Electrochemistry can bring important contributions to current applications, such as organic synthesis or wastewater treatment. In an environmental context, electrochemical processes are interesting substitutes to the conventional wastewater treatment techn ...
The electrochem. promotion of RuO2 catalysts interfaced with yttria stabilized zirconia was studied for the combustion of ethylene. The complete oxidn. of ethylene can be described by an Eley-Rideal type mechanism. In situ work function measurements were u ...
The Cl2 evolution reaction was studied at highly boron-doped diamond thin film electrodes. The comparison of this carbonaceous material with graphite and glassy carbon points out the similar behavior in terms of diagnostic parameters and related mechanisms ...
The electrochem. oxidn. (or combustion) of orgs. with simultaneous oxygen evolution has been investigated using different oxide electrodes. A simplified mechanism for the electrochem. oxidn. of orgs. is presented, according to which selective oxidn. occurs ...
The electrochem. oxidn. (or combustion) of orgs. with simultaneous oxygen evolution was studied using different electrode materials (Ti/IrO2, Ti/SnO2). A simplified mechanism for the electrochem. oxidn. of orgs. is presented, according to which selective o ...