Environmental effects on the energetics and photoinduced dynamics of molecular states
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The structural changes due to formation of electronic bubbles in solid D2 are studied by fluorescence, fluorescence-excitation, and fluorescence-depletion spectroscopy of the lowest Rydberg state, A 2S+(3ss), of the NO impurity. The A X band is strongly bl ...
Excitation of the A(3ss) Rydberg state of NO leads to an extensive rearrangement of the environment, which was studied by classical mol. dynamics simulations and normal mode anal., using pair potentials from the literature. The medium response is independe ...
Upon treating elemental S with [AgSbF6], [AgAl(hfip)4], [AgAl(pftb)4] (hfip = OCH(CF3)2, pftb = OC(CF3)3), [Ag(S8)2][SbF6] (1), [AgS8][Al(hfip)4] (2), and [Ag(S8)2]+[Al(pftb)4]- (3) formed in SO2 (1), CS2 (2), or CH2Cl2 (3). 1-3 Were characterized by singl ...
Emission, absorption, and excitation spectroscopy was used for a detailed anal. of the optical transitions of Hg2 trapped in cryogenic matrixes. Upon excitation of electronic states correlating to the 3P1 or the 1P1 asymptote, fast nonradiative relaxation ...
The dynamics of electron bubble formation upon excitation of the A(3ss) Rydberg orbital of NO in solid Ne was studied by femtosecond pump-probe spectroscopy. The authors observe an ultrafast expansion of the bubble, followed by a vibrational recurrence in ...
In this note the S‐matrix naturally associated with a singularly perturbed three‐dimensional system of linear differential equations without turning point on the real axis is considered. It is shown that for a fairly large class of examples, the Complex WK ...
The dynamics of non-polar electronic solvation has been studied on a model system consisting of NO-doped solid Ar. Excitation of the lowest Rydberg state A(3ss) of NO leads to formation of an electronic 'bubble', which has been studied by femtosecond pump- ...
By analyzing the vibrational eigenmodes of a model structure obtained previously by quantum molecular dynamics, the two sharp features appearing in the Raman spectrum of vitreous silica could conclusively be assigned to three- and four-membered ring struct ...
The past ten years of developmental genetics have revealed that most of our genes are shared by other species throughout the animal kingdom. Consequently, animal diversity might largely rely on the differential use of the same components, either at the ind ...
Higher Rydberg states of NO trapped in rare gas matrixes were studied by inducing Rydberg-Rydberg transitions from the lowest A2S+ (3ss) Rydberg state and detecting its fluorescence depletion. This technique unravels Rydberg states, which cannot be accesse ...