Experimental evidence to Rydbergization of antibonding molecular orbitals
Graph Chatbot
Chattez avec Graph Search
Posez n’importe quelle question sur les cours, conférences, exercices, recherches, actualités, etc. de l’EPFL ou essayez les exemples de questions ci-dessous.
AVERTISSEMENT : Le chatbot Graph n'est pas programmé pour fournir des réponses explicites ou catégoriques à vos questions. Il transforme plutôt vos questions en demandes API qui sont distribuées aux différents services informatiques officiellement administrés par l'EPFL. Son but est uniquement de collecter et de recommander des références pertinentes à des contenus que vous pouvez explorer pour vous aider à répondre à vos questions.
In plane wave based electronic structure calcns. the interactions between core and valence electrons are in general represented by effective core potentials. These pseudopotentials are usually constructed such that the shape of the at. valence orbitals out ...
We present internal-photoemission (photocurrent) experimental evidence for a Fano resonance at an n-p GaAs homojunction with a 0.5-ML Si intralayer (delta doping). This is one of a very few cases in which Fano resonances have been observed in artificial na ...
Radiative transfer is often the dominant energy transport channel in inertial confinement fusion experiments. It is a basic process needed in order to understand the behaviour of astrophysical plasmas, like stellar atmospheres and the inner parts of stars. ...
Individual MO (MO) contributions to the magnetic shielding of atoms as well as to the nucleus-independent chem. shifts (NICS) of arom. compds. can be computed by the widely used gauge-including AO (GIAO) method. Detailed analyses of magnetic shielding MO-N ...
The ultrafast dynamics are reported of bubble formation following excitation of the A 2S+ 3ss(v = 0) Rydberg state of NO trapped in Ar matrixes. The study is carried out by a fs pump-probe technique. The detected signal is the depletion of Rydberg fluoresc ...
D. effects and N2 co-doping of Kr solids doped with NO allow continuous tuning of the NO Rydberg state energies in a range 0.35 to 0.68 eV blue of the gas phase. This property is exploited to control the vibronic configuration mixing between the Rydberg C2 ...
New experimental results are reported on state-dependent steric effects in NO-Ar inelastic scattering. The NO molecules are selected in the J = 1/2(-) l-doublet state of the electronic ground state and oriented relative to the incident Ar atoms. The steric ...
Rydberg-Rydberg transitions are induced by absorption from the lowest Rydberg state of NO A 2S+ (3ss) in Ar matrixes, which is excited by an ArF laser at 193.3 nm. The depopulation of the A(v = 0) level to higher Rydberg states is probed by depletion of it ...
Novel x-ray spectroscopies such as high-resolution x-ray absorption (XAS) performed in the partial fluorescence yield mode (PFY), and resonant emission (RXES) offer new opportunities to probe the bulk electronic configuration in strongly correlated systems ...
The dynamics of electron bubble formation upon excitation of the A(3ss) Rydberg orbital of NO in solid Ne was studied by femtosecond pump-probe spectroscopy. The authors observe an ultrafast expansion of the bubble, followed by a vibrational recurrence in ...
