Experimental evidence to Rydbergization of antibonding molecular orbitals
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The dynamics of electron bubble formation upon excitation of the A(3ss) Rydberg orbital of NO in solid Ne was studied by femtosecond pump-probe spectroscopy. The authors observe an ultrafast expansion of the bubble, followed by a vibrational recurrence in ...
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Rydberg-Rydberg transitions are induced by absorption from the lowest Rydberg state of NO A 2S+ (3ss) in Ar matrixes, which is excited by an ArF laser at 193.3 nm. The depopulation of the A(v = 0) level to higher Rydberg states is probed by depletion of it ...
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New experimental results are reported on state-dependent steric effects in NO-Ar inelastic scattering. The NO molecules are selected in the J = 1/2(-) l-doublet state of the electronic ground state and oriented relative to the incident Ar atoms. The steric ...
The ultrafast dynamics are reported of bubble formation following excitation of the A 2S+ 3ss(v = 0) Rydberg state of NO trapped in Ar matrixes. The study is carried out by a fs pump-probe technique. The detected signal is the depletion of Rydberg fluoresc ...
D. effects and N2 co-doping of Kr solids doped with NO allow continuous tuning of the NO Rydberg state energies in a range 0.35 to 0.68 eV blue of the gas phase. This property is exploited to control the vibronic configuration mixing between the Rydberg C2 ...
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Radiative transfer is often the dominant energy transport channel in inertial confinement fusion experiments. It is a basic process needed in order to understand the behaviour of astrophysical plasmas, like stellar atmospheres and the inner parts of stars. ...
In plane wave based electronic structure calcns. the interactions between core and valence electrons are in general represented by effective core potentials. These pseudopotentials are usually constructed such that the shape of the at. valence orbitals out ...
