Probing the Electronic Structure of the Hemoglobin Active Center in Physiological Solutions
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Synthesis of the tricoordinated alanyl-contg. iron complex [(tmp)2Al-Fe(Cp)(CO)2] (1) (tmp = 2,2,6,6-tetramethylpiperidino) has been achieved in a straightforward salt elimination reaction of (tmp)2AlBr with Na[(Cp)Fe(CO)2]. 1 Crystallizes in the triclinic ...
The membrane-bound tetrachloroethene reductive dehalogenase (PCE-RDase) (PceA; EC 1.97.1.8), the terminal component of the respiratory chain of Dehalobacter restrictus, was purified 25-fold to apparent electrophoretic homogeneity. Sodium dodecyl sulfate-po ...
The two known Me- and allyl-substituted 1H-imidazol-3-ium bromides 1 and 2, respectively, were converted to the corresponding BF4- and BPh4- salts 3-6 (Scheme 1). Compounds 3 and 4 were liquids at ambient temperature. Reaction of 1 or 2 with [PdCl2] afford ...
This study presents the detailed nature of iron clusters formed on Fe3+-Nafion membranes. The catalytic nature of these clusters during immobilized Fenton processes was observed to be a function of the deposition method of Fe ions on the Nafion. The nonbio ...
