Simulation of self-assembled monolayers:microscopic structure of amino alkylthiols
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Physisorbed and covalently bound Langmuir-Blodgett (LB) monolayers of sulfur-bearing lipids on mica and on gold substrates, resp., have been studied. Scanning force microscopy, in topog. and friction modes as well as in contact and non-contact modes have b ...
We report on a multi-technique investigation of the supramolecular organisation of N,N-diphenyl oxalic amide under differently dimensioned environments, namely three-dimensional (3D) in the bulk crystal, and in two dimensions on the Ag(111) surface as well ...
A simple method has been developed for the prodn. of Au surfaces which are uniformly flat over large areas. Si wafers serve as substrates for the evapn. of thin Au layers. A glass slide glued onto the Au film allows successful sepn. of the Au layer from th ...
This thesis deals with the self-organization of individual building blocks, specifically organic molecules and metal atoms, into supramolecular structures on metal surfaces under ultra high vacuum conditions (UHV). Self-organization of supramolecular syste ...
Scanning tunneling microscopy reveals, at single-molecular resolution, how external parameters-substrate morphology and guest addition-re-direct the assembly of dumbbell-shaped coordination supramolecules towards different surfaceconfined supramolecular or ...
The adsorption of terephthalic acid [C6H4(COOH)(2), TPA] on a Pd(111) surface has been investigated by means of scanning tunneling microscopy (STM), x-ray photoelectron spectroscopy, and near-edge x-ray absorption fine structure spectroscopy under ultrahig ...
A biocompatible interface was constructed on a microchip by using the layer-by-layer (LBL) assembly of charged polysaccharides incorporating proteases for highly efficient proteolysis. The controlled assembly of natural polyelectrolytes and the enzyme-adso ...
Monolayers of thiols self-assembled on Au (111) can be made hydrophilic by functionalizing the surface with polar endgroups. The authors present scanning tunneling microscopy (STM) images of 2 such hydrophilic monolayers, one terminated by hydroxyl (mercap ...
Lateral force microscopy in the wearless regime was used to study the friction behavior of a lipid monolayer on mica. In the monolayer, condensed domains with long-range orientational order of the lipid molecules were present. The domains revealed unexpect ...
American Association for the Advancement of Science (AAAS)1998