Isopulegol as a model compound. Metalation and substitution of an allylic position in the presence of an unprotected hydroxy function
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Let A be a d-dimensional smooth algebra over a perfect field of characteristic not 2. Let Um(n+1)(A)/En+1 (A) be the set of unimodular rows of length n + 1 up to elementary transformations. If n >= (d + 2)/2, it carries a natural structure of group as disc ...
The direct and enantioselective functionalization of inert bonds such as carbon-hydrogen and carbon-carbon is an emerging tool towards more sustainable and efficient synthetic methods. The individual activation pathways like concerted deprotonation metalat ...
We determine the torsion subgroup of the group of endotrivial modules for a finite solvable group in characteristic p. We also prove that our result would hold for p-solvable groups, provided a conjecture can be proved about the case of p-nilpotent groups. ...
The integrated approach for the design of solid catalysts for process intensification is presented addressing simultaneously different levels of scale and complexity involved in the development starting from the molecular/nano-scale of the active phase opt ...
The rapid development of derandomization theory, which is a fundamental area in theoretical computer science, has recently led to many surprising applications outside its initial intention. We will review some recent such developments related to combinator ...
Although research and development (R&D) networks influence the innovation performance of their members, firms may not be fully aware of the scope of their network. In particular, due to cost reasons, they may not be fully informed of their “indirect ties”, ...
In this paper we discuss our experience designing and collecting a data corpus called ELEA (Emergent LEader Analysis), and describe the use of a light portable scenario to record small group meetings. The corpus was gathered with the aim of analyzing emerg ...
In this paper, we consider the problem of manifold approximation with affine subspaces. Our objective is to discover a set of low dimensional affine subspaces that represents manifold data accurately while preserving the manifold’s structure. For this purp ...
We consider a group of m trusted nodes that aim to create a shared secret key K, using a state-dependent wireless broadcast channel that exists from one of the honest nodes to the rest of the nodes including a passive eavesdropper Eve. All of the trusted n ...
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Given a principal bundle G hooked right arrow P -> B (each being compact, connected and oriented) and a G-invariant metric h(P) on P which induces a volume form mu(P), we consider the group of all unimodular automorphisms SAut(P, mu(P)) := {phi is an eleme ...