A thermodynamic model for the precipitation of nanostructured copper oxalates
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Powder synchrotron X-ray diffraction studies confirm that 7-oxabicyclo[2.2.1]heptane, (oxanorbornane), forms three solid phases on cooling and four on warming, as previously indicated by spectroscopic and DSC meas urements. The two highest temperature phas ...
The ion pair of the stereolabile C3-symmetric, i+o proton complex [1⋅H]+ of diaza-macropentacycle 1 and the configurationally stable Δ-TRISPHAT ([Δ-3]−) anion exists in the form of two diastereomers, namely, [Δ-(1⋅H)][Δ-3] and [Λ-(1⋅H)][Δ-3], the ratio of ...
We studied the phase behavior of a model binary mixture of eye lens crystallin proteins using first-order thermodynamic perturbation theory. The instability boundary, or spinodal surface, was found to be very sensitive to the strength of the attraction bet ...
This study presents ISORROPIA II, a thermodynamic equilibrium model for the K+-Ca2+-Mg2+-NH4 +-Na+-SO42--NO3 --Cl--H2O aerosol system. A comprehensive evaluation of its performance is conducted against water uptake measurements for laboratory aerosol and p ...
The Cu-Ge binary system was assessed thermodynamically using the CALPHAD method through Thermocalc (R) software package based on the evaluation of all available experimental data from the published literature. The solution phases, including liquid, fcc, hc ...
Many of the complex physical processes relevant for compositional multi-phase flow in porous media are well understood at the pore-scale level. In order to study CO2 storage in sub-surface formations, however, it is not feasible to perform simulations at t ...
The influence of the presence of limestone on the hydration of Portland cement was investigated. Blending of Portland cement with limestone was found to influence the hydrate assemblage of the hydrated cement. Thermodynamic calculations as well as experime ...
A review. This review addresses the catalytic reactions performed in microstructured reactors, which are more and more recognized in recent years as a novel approach for chem. and chem. process industry. They are particularly suited for highly exothermic a ...
Directional solidification experiments on Cu-Sn peritectic alloys have been conducted at very low velocity in a high-thermal-gradient Bridgman furnace. The size of the samples has been reduced in order to decrease natural convection and the associated macr ...