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The aim of this thesis was to investigate the process-structure-property relationships of UV-curable hyperbranched polymer (HBP)/silica nanocomposites. Special attention was paid to the interplay between photo-conversion, rheological behavior, shrinkage, a ...
The overall aim of this thesis has been to assess the potential of latex-based technologies for the preparation of polymer/clay nanocomposites. The key feature of latex-based technologies is that they offer the possibility of improved control of the final ...
A difunctional cycloaliphatic epoxy monomer was cationically photo-polymerized in the presence of a diaryliodonium salt photoinitiator and an isopropyl thioxanthone photosensitizer at different temperatures and UV intensities. The photo-polymerization kine ...
The intervertebral disc (IVD), which provides flexibility to the spine and facilitates damping and motion, is composed of two distinct structures: the annulus fibrosus (AF) and the nucleus pulposus (NP). The AF, which is fibrous and elastic, confines the N ...
Hydrogels are cross-linked, water-swollen polymer networks that are widely used as a biomaterial. Because of high amount of water, they are mechanically poor and soft. This aspect limits their applications. The suitability of hydrogels as biomedical materi ...
A definition of macromolecular science (as opposed to polymer science and engineering) is given, from which the year 1930 is derived as the year of its birth. The scope of treatment of this paper will be limited to solid technical polymers. Some important ...
The effect of low-temperature curing on the physical characteristics of a commercial cold-curing epoxy adhesive was experimentally and analytically investigated with a view to a potential application in bridge construction in winter. Curing at low temperat ...
Dielectric elastomers are highly promising as functional materials for the rapidly developing field of flexible actuator and generator technology. They offer a unique combination of low densities and large reversible deformations of up to more than 100% in ...
We investigate the structural, dynamical, and rheological properties of colloid-polymer mixtures in a volume fraction range of φ=0.15-0.35. Our systems are density-matched, residual charges are screened, and the polymer-colloid size ratio is ∼0.37. For the ...
Nanocomposite materials based on a HBP and silica are produced using either a dual-cure sol/gel and photopolymerization process or by mixing silica nanoparticles with the HBP. In both cases the conversion of the HBP is independent of composition and obeys ...
