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Hydrogels are cross-linked, water-swollen polymer networks that are widely used as a biomaterial. The suitability of hydrogels as biomedical materials, especially as drug delivery systems depend on their bulk structure. The most important parameters used t ...
In various single-molecule experiments, a chiral polymer, such as DNA, is simultaneously pulled and twisted. We address an elementary but fundamental question raised by various authors: does the molecule overwind or unwind under tension? We show that withi ...
In this thesis, we proposed to study polymer-based thick-film resistors (TFRs) made of graphite particles dispersed in an epoxy matrix. Three main axes were investigated: formulation of the composites, characterization with the determination of electrical, ...
A new method for generating a surface density gradient of polymer chains is presented. A substrate-independent polymer deposition technique was used to coat materials with a chemical gradient based on plasma copolymerization of 1,7-octadiene and allylamine ...
We report on the modeling of a photopolymerizable hydrogel and its application as a replacement of the interior of the intervertebral disc (so called Nucleus Pulposus). The hydrogel is initially injected in its liquid form and then photopolymerized via a s ...
Copolymers of fluoroacrylates have interesting properties like excellent resistance to chemicals, oils and fuels, high thermal stability and high hydrophobicity. This investigation reports the copolymerization of 2,2,3,3,4,4,4-heptafluorobutyl acrylate (HF ...
Self-healing materials are a novel class of materials able to repair structural or, more generally, functional damage to a part. They hence have the potential to improve reliability and cost effectiveness, because failure or loss of functionality may be po ...
The aim of this thesis has been to investigate the use of heat-activated shape memory polymers (SMPs) as novel smart actuators for the controlled delivery of fluids and their suitability for applications such as low-cost drug delivery. On heating to temper ...
Petroleum-based polymers and composites are commonly used in a wide variety of application fields. However ecological concerns, increasing oil prices and dwindling natural resources explain why nowadays industrial and public interest is more than ever focu ...
This work addresses the development of composite materials that contain metallic load-bearing cords with the aim of combining outstanding mechanical performance with added functionality, including electrical conductivity, data transmission, and temperature ...
